Home > Publications database > Structure, Magnetism, and the Magnetocaloric Effect of MnFe$_{4}$Si$_{3}$ Single Crystals and Powder Samples > print

001     256615
005     20250129094237.0
024 7 _ |2 doi
|a 10.1021/acs.chemmater.5b03123
024 7 _ |2 ISSN
|a 0897-4756
024 7 _ |2 ISSN
|a 1520-5002
024 7 _ |2 WOS
|a WOS:000363915000026
037 _ _ |a FZJ-2015-06482
082 _ _ |a 540
100 1 _ |0 P:(DE-Juel1)156570
|a Hering, Paul
|b 0
245 _ _ |a Structure, Magnetism, and the Magnetocaloric Effect of MnFe$_{4}$Si$_{3}$ Single Crystals and Powder Samples
260 _ _ |a Washington, DC
|b American Chemical Society
|c 2015
336 7 _ |0 PUB:(DE-HGF)16
|2 PUB:(DE-HGF)
|a Journal Article
|b journal
|m journal
|s 1457095142_14709
336 7 _ |2 DataCite
|a Output Types/Journal article
336 7 _ |0 0
|2 EndNote
|a Journal Article
336 7 _ |2 BibTeX
|a ARTICLE
336 7 _ |2 ORCID
|a JOURNAL_ARTICLE
336 7 _ |2 DRIVER
|a article
520 _ _ |a Magnetic and structural properties of high quality magnetocaloric MnFe4Si3 single crystals are investigated macroscopically and on an atomic scale. Refinements of combined neutron and X-ray single crystal diffraction data introduce a new structural model in space group P6 characterized by partial ordering of Mn and Fe into layers perpendicular to c on one of the transition metal sites. A second transition metal site is exclusively occupied by iron. MnFe4Si3 has a phase transition to a ferromagnetically ordered phase at approximately 300 K and displays a strong anisotropy of the magnetization and the magnetocaloric effect with the easy axis of magnetization in the a,b-plane. This is confirmed by a refinement of the magnetic structure in the magnetic spacegroup Pm′, which shows that the spins on the sites with mixed occupancy of Mn and Fe are aligned in the a,b-plane. A significant magnetic moment for the site exclusively occupied by iron could not be refined. The thermal evolution of the lattice parameters exhibits an anisotropic behavior and clearly reflects the onset of magnetic ordering. A comparison of the ordered moment and the effective paramagnetic moment hints toward itinerant magnetism in the system.
536 _ _ |0 G:(DE-HGF)POF3-144
|a 144 - Controlling Collective States (POF3-144)
|c POF3-144
|f POF III
|x 0
536 _ _ |0 G:(DE-HGF)POF3-524
|a 524 - Controlling Collective States (POF3-524)
|c POF3-524
|f POF III
|x 1
536 _ _ |0 G:(DE-HGF)POF3-6212
|a 6212 - Quantum Condensed Matter: Magnetism, Superconductivity (POF3-621)
|c POF3-621
|f POF III
|x 2
536 _ _ |0 G:(DE-HGF)POF3-6213
|a 6213 - Materials and Processes for Energy and Transport Technologies (POF3-621)
|c POF3-621
|f POF III
|x 3
536 _ _ |0 G:(DE-HGF)POF3-6G4
|a 6G4 - Jülich Centre for Neutron Research (JCNS) (POF3-623)
|c POF3-623
|f POF III
|x 4
588 _ _ |a Dataset connected to CrossRef
650 2 7 |0 V:(DE-MLZ)SciArea-170
|2 V:(DE-HGF)
|a Magnetism
|x 0
650 1 7 |a Chemical Reactions and Advanced Materials
|0 V:(DE-MLZ)GC-1603-2016
|2 V:(DE-HGF)
|x 1
650 1 7 |a Key Technologies
|0 V:(DE-MLZ)GC-150-1
|2 V:(DE-HGF)
|x 0
693 _ _ |0 EXP:(DE-MLZ)SPODI-20140101
|1 EXP:(DE-MLZ)FRMII-20140101
|5 EXP:(DE-MLZ)SPODI-20140101
|6 EXP:(DE-MLZ)SR8a-20140101
|a Forschungs-Neutronenquelle Heinz Maier-Leibnitz
|e SPODI: High resolution powder diffractometer
|f SR8a
|x 0
700 1 _ |0 P:(DE-Juel1)145694
|a Friese, Karen
|b 1
|e Corresponding author
700 1 _ |0 P:(DE-Juel1)131018
|a Voigt, Jörg
|b 2
700 1 _ |0 P:(DE-Juel1)130884
|a Persson, Jörg
|b 3
700 1 _ |0 P:(DE-HGF)0
|a Aliouane, Nadir
|b 4
700 1 _ |0 P:(DE-HGF)0
|a Grzechnik, Andrzej
|b 5
700 1 _ |0 P:(DE-HGF)0
|a Senyshyn, Anatoliy
|b 6
700 1 _ |0 P:(DE-Juel1)130572
|a Brückel, Thomas
|b 7
773 _ _ |0 PERI:(DE-600)1500399-1
|a 10.1021/acs.chemmater.5b03123
|g Vol. 27, no. 20, p. 7128 - 7136
|n 20
|p 7128 - 7136
|t Chemistry of materials
|v 27
|x 1520-5002
|y 2015
856 4 _ |u https://juser.fz-juelich.de/record/256615/files/acs.chemmater.5b03123.pdf
|y Restricted
856 4 _ |u https://juser.fz-juelich.de/record/256615/files/acs.chemmater.5b03123.gif?subformat=icon
|x icon
|y Restricted
856 4 _ |u https://juser.fz-juelich.de/record/256615/files/acs.chemmater.5b03123.jpg?subformat=icon-1440
|x icon-1440
|y Restricted
856 4 _ |u https://juser.fz-juelich.de/record/256615/files/acs.chemmater.5b03123.jpg?subformat=icon-180
|x icon-180
|y Restricted
856 4 _ |u https://juser.fz-juelich.de/record/256615/files/acs.chemmater.5b03123.jpg?subformat=icon-640
|x icon-640
|y Restricted
856 4 _ |u https://juser.fz-juelich.de/record/256615/files/acs.chemmater.5b03123.pdf?subformat=pdfa
|x pdfa
|y Restricted
909 C O |o oai:juser.fz-juelich.de:256615
|p VDB:MLZ
|p VDB
910 1 _ |0 I:(DE-588b)5008462-8
|6 P:(DE-Juel1)156570
|a Forschungszentrum Jülich GmbH
|b 0
|k FZJ
910 1 _ |0 I:(DE-588b)5008462-8
|6 P:(DE-Juel1)145694
|a Forschungszentrum Jülich GmbH
|b 1
|k FZJ
910 1 _ |0 I:(DE-588b)5008462-8
|6 P:(DE-Juel1)131018
|a Forschungszentrum Jülich GmbH
|b 2
|k FZJ
910 1 _ |0 I:(DE-588b)5008462-8
|6 P:(DE-Juel1)130884
|a Forschungszentrum Jülich GmbH
|b 3
|k FZJ
910 1 _ |0 I:(DE-588b)5008462-8
|6 P:(DE-Juel1)130572
|a Forschungszentrum Jülich GmbH
|b 7
|k FZJ
913 1 _ |0 G:(DE-HGF)POF3-144
|1 G:(DE-HGF)POF3-140
|2 G:(DE-HGF)POF3-100
|a DE-HGF
|l Future Information Technology - Fundamentals, Novel Concepts and Energy Efficiency (FIT)
|v Controlling Collective States
|x 0
|4 G:(DE-HGF)POF
|3 G:(DE-HGF)POF3
|b Energie
913 1 _ |0 G:(DE-HGF)POF3-524
|1 G:(DE-HGF)POF3-520
|2 G:(DE-HGF)POF3-500
|a DE-HGF
|b Key Technologies
|l Future Information Technology - Fundamentals, Novel Concepts and Energy Efficiency (FIT)
|v Controlling Collective States
|x 1
|4 G:(DE-HGF)POF
|3 G:(DE-HGF)POF3
913 1 _ |0 G:(DE-HGF)POF3-621
|1 G:(DE-HGF)POF3-620
|2 G:(DE-HGF)POF3-600
|9 G:(DE-HGF)POF3-6212
|a DE-HGF
|b Forschungsbereich Materie
|l Von Materie zu Materialien und Leben
|v In-house research on the structure, dynamics and function of matter
|x 2
|4 G:(DE-HGF)POF
|3 G:(DE-HGF)POF3
913 1 _ |0 G:(DE-HGF)POF3-621
|1 G:(DE-HGF)POF3-620
|2 G:(DE-HGF)POF3-600
|9 G:(DE-HGF)POF3-6213
|a DE-HGF
|b Forschungsbereich Materie
|l Von Materie zu Materialien und Leben
|v In-house research on the structure, dynamics and function of matter
|x 3
|4 G:(DE-HGF)POF
|3 G:(DE-HGF)POF3
913 1 _ |0 G:(DE-HGF)POF3-623
|1 G:(DE-HGF)POF3-620
|2 G:(DE-HGF)POF3-600
|9 G:(DE-HGF)POF3-6G4
|a DE-HGF
|b Forschungsbereich Materie
|l Von Materie zu Materialien und Leben
|v Facility topic: Neutrons for Research on Condensed Matter
|x 4
|4 G:(DE-HGF)POF
|3 G:(DE-HGF)POF3
914 1 _ |y 2015
915 _ _ |0 StatID:(DE-HGF)0420
|2 StatID
|a Nationallizenz
915 _ _ |0 StatID:(DE-HGF)0100
|2 StatID
|a JCR
|b CHEM MATER : 2014
915 _ _ |0 StatID:(DE-HGF)0200
|2 StatID
|a DBCoverage
|b SCOPUS
915 _ _ |0 StatID:(DE-HGF)0300
|2 StatID
|a DBCoverage
|b Medline
915 _ _ |0 StatID:(DE-HGF)0199
|2 StatID
|a DBCoverage
|b Thomson Reuters Master Journal List
915 _ _ |0 StatID:(DE-HGF)0110
|2 StatID
|a WoS
|b Science Citation Index
915 _ _ |0 StatID:(DE-HGF)0150
|2 StatID
|a DBCoverage
|b Web of Science Core Collection
915 _ _ |0 StatID:(DE-HGF)0111
|2 StatID
|a WoS
|b Science Citation Index Expanded
915 _ _ |0 StatID:(DE-HGF)1150
|2 StatID
|a DBCoverage
|b Current Contents - Physical, Chemical and Earth Sciences
915 _ _ |0 StatID:(DE-HGF)1160
|2 StatID
|a DBCoverage
|b Current Contents - Engineering, Computing and Technology
915 _ _ |0 StatID:(DE-HGF)9905
|2 StatID
|a IF >= 5
|b CHEM MATER : 2014
920 1 _ |0 I:(DE-Juel1)JCNS-2-20110106
|k JCNS-2
|l Streumethoden
|x 0
920 1 _ |0 I:(DE-Juel1)PGI-4-20110106
|k PGI-4
|l Streumethoden
|x 1
920 1 _ |0 I:(DE-82)080009_20140620
|k JARA-FIT
|l JARA-FIT
|x 2
920 1 _ |0 I:(DE-Juel1)JCNS-FRM-II-20110218
|k JCNS (München) ; Jülich Centre for Neutron Science JCNS (München) ; JCNS-FRM-II
|l JCNS-FRM-II
|x 3
980 _ _ |a journal
980 _ _ |a VDB
980 _ _ |a I:(DE-Juel1)JCNS-2-20110106
980 _ _ |a I:(DE-Juel1)PGI-4-20110106
980 _ _ |a I:(DE-82)080009_20140620
980 _ _ |a I:(DE-Juel1)JCNS-FRM-II-20110218
980 _ _ |a UNRESTRICTED
981 _ _ |a I:(DE-Juel1)JCNS-2-20110106
981 _ _ |a I:(DE-Juel1)PGI-4-20110106
981 _ _ |a I:(DE-Juel1)JCNS-FRM-II-20110218

LibraryCollectionCLSMajorCLSMinorLanguageAuthor
Marc 21