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001     26705
005     20200423203415.0
024 7 _ |a pmid:12465979
|2 pmid
024 7 _ |a 10.1021/ja026585+
|2 DOI
024 7 _ |a WOS:000179661000040
|2 WOS
024 7 _ |a 2128/2066
|2 Handle
037 _ _ |a PreJuSER-26705
041 _ _ |a eng
082 _ _ |a 540
084 _ _ |2 WoS
|a Chemistry, Multidisciplinary
100 1 _ |a Silin, F. H.
|b 0
|0 P:(DE-HGF)0
245 _ _ |a The role of surface free energy on the formation of hybrid bilayer membranes
260 _ _ |a Washington, DC
|b American Chemical Society
|c 2002
300 _ _ |a 14676
336 7 _ |a Journal Article
|0 PUB:(DE-HGF)16
|2 PUB:(DE-HGF)
336 7 _ |a Output Types/Journal article
|2 DataCite
336 7 _ |a Journal Article
|0 0
|2 EndNote
336 7 _ |a ARTICLE
|2 BibTeX
336 7 _ |a JOURNAL_ARTICLE
|2 ORCID
336 7 _ |a article
|2 DRIVER
440 _ 0 |a Journal of the American Chemical Society
|x 0002-7863
|0 8502
|v 124
500 _ _ |a Record converted from VDB: 12.11.2012
520 _ _ |a The interaction of small phospholipid vesicles with well-characterized surfaces has been studied to assess the effect of the surface free energy of the underlying monolayer on the formation of phospholipid/alkanethiol hybrid bilayer membranes (HBMs). The surface free energy was changed in a systematic manner using single-component alkanethiol monolayers and monolayers of binary mixtures of thiols. The binary surfaces were prepared on gold by self-assembly from binary solutions of the thiols HS-(CH(2))(n)()-X (n = 11, X = CH(3) or OH) in THF. Surface plasmon resonance (SPR), electrical capacitance, and atomic force microscopy (AFM) measurements were used to characterize the interaction of palmitoyl,oleoyl-phosphatidylcholine (POPC) vesicles with the surfaces. For all surfaces examined, it appears that the polar part of surface energy influences the nature of the POPC assembly that associates with the surface. Comparison of optical, capacitance, and AFM data suggests that vesicles can remain intact or partially intact even at surfaces with a contact angle with water of close to 100 degrees. In addition, comparison of the alkanethiols of different chain lengths and the fluorinated compound HS-(CH(2))(2)-(CF(2))(8)-CF(3) that characterize with a low value of the polar part of the surface energy suggests that the quality of the underlying monolayer in terms of number of defects has a significant influence on the packing density of the resulting HBM layer.
536 _ _ |a Materialien, Prozesse und Bauelemente für die Mikro- und Nanoelektronik
|c I01
|2 G:(DE-HGF)
|0 G:(DE-Juel1)FUEK252
|x 0
588 _ _ |a Dataset connected to Web of Science, Pubmed
650 _ 2 |2 MeSH
|a Adsorption
650 _ 2 |2 MeSH
|a Alkanes: chemistry
650 _ 2 |2 MeSH
|a Electric Capacitance
650 _ 2 |2 MeSH
|a Hydrocarbons, Fluorinated: chemistry
650 _ 2 |2 MeSH
|a Kinetics
650 _ 2 |2 MeSH
|a Lipid Bilayers: chemistry
650 _ 2 |2 MeSH
|a Membranes: chemistry
650 _ 2 |2 MeSH
|a Microscopy, Atomic Force
650 _ 2 |2 MeSH
|a Phosphatidylcholines: chemistry
650 _ 2 |2 MeSH
|a Sulfhydryl Compounds: chemistry
650 _ 2 |2 MeSH
|a Surface Plasmon Resonance
650 _ 2 |2 MeSH
|a Surface Properties
650 _ 2 |2 MeSH
|a Thermodynamics
650 _ 7 |0 0
|2 NLM Chemicals
|a Alkanes
650 _ 7 |0 0
|2 NLM Chemicals
|a Hydrocarbons, Fluorinated
650 _ 7 |0 0
|2 NLM Chemicals
|a Lipid Bilayers
650 _ 7 |0 0
|2 NLM Chemicals
|a Phosphatidylcholines
650 _ 7 |0 0
|2 NLM Chemicals
|a Sulfhydryl Compounds
650 _ 7 |0 112-40-3
|2 NLM Chemicals
|a n-dodecane
650 _ 7 |0 6753-55-5
|2 NLM Chemicals
|a 1-palmitoyl-2-oleoylphosphatidylcholine
650 _ 7 |a J
|2 WoSType
700 1 _ |a Wieder, H.
|b 1
|0 P:(DE-HGF)0
700 1 _ |a Woodward, J. T.
|b 2
|0 P:(DE-HGF)0
700 1 _ |a Valincius, G.
|b 3
|0 P:(DE-HGF)0
700 1 _ |a Offenhäusser, A.
|b 4
|u FZJ
|0 P:(DE-Juel1)128713
700 1 _ |a Plant, A. L.
|b 5
|u FZJ
|0 P:(DE-Juel1)VDB11929
773 _ _ |a 10.1021/ja026585+
|g Vol. 124, p. 14676
|p 14676
|q 124<14676
|0 PERI:(DE-600)1472210-0
|t Journal of the American Chemical Society
|v 124
|y 2002
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913 1 _ |k I01
|v Materialien, Prozesse und Bauelemente für die Mikro- und Nanoelektronik
|l Informationstechnologie mit nanoelektronischen Systemen
|b Information
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914 1 _ |a Nachtrag
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915 _ _ |0 StatID:(DE-HGF)0010
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920 1 _ |k ISG-2
|l Institut für Bio- und Chemosensoren
|d 31.12.2006
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