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@ARTICLE{Ziebinska:2738,
author = {Ziebinska, A. and Rytz, D. and Szot, K.},
title = {{B}irefringence above ${T}_c$ in single crystals of barium
titanate},
journal = {Journal of physics / Condensed matter},
volume = {20},
issn = {0953-8984},
address = {Bristol},
publisher = {IOP Publ.},
reportid = {PreJuSER-2738},
pages = {142202},
year = {2008},
note = {Record converted from VDB: 12.11.2012},
abstract = {The temperature dependence of the birefringence above T-c
in high quality BaTiO3 single crystals has been measured
with very high accuracy. On the basis of literature data,
the behaviour of the anomalous birefringence can be
explained by the existence of polar clusters
(microregions/nanoregions) connected with correlated jumps
between the off-centre positions of Ti ions inside the
oxygen octahedra. The underlying origin of the polar
clusters is an intrinsic effect connected with the
interdependence of the structural and polar soft modes
(Bussmann-Holder et al 2007 Phys. Rev. Lett. 99 167603).
These clusters locally break the intrinsic cubic symmetry
and the phase above T-c becomes birefringent. A
birefringence Delta n of the order of 10(-5) has been found
up to about 30 degrees above T-c. In this temperature range
T-c < T < T-c + 30 K, the function Delta n(T) exhibits a
thermal hysteresis: the values of Delta n were higher on
heating than on cooling. A characteristic feature is the
existence of a local Delta n(T) maximum at a temperature
close to T-c on the high temperature side that appears due
to a specific cluster-cluster interaction. Since the values
of Delta n(T) runs were not dependent on the crystal
thickness, one can conclude that in this limited temperature
range above T-c the birefringence is an inherent feature of
the crystal.},
keywords = {J (WoSType)},
cin = {IFF-6 / JARA-FIT},
ddc = {530},
cid = {I:(DE-Juel1)VDB786 / $I:(DE-82)080009_20140620$},
pnm = {Grundlagen für zukünftige Informationstechnologien},
pid = {G:(DE-Juel1)FUEK412},
shelfmark = {Physics, Condensed Matter},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000254175100002},
doi = {10.1088/0953-8984/20/14/142202},
url = {https://juser.fz-juelich.de/record/2738},
}