guest ::
| Home > Publications database > Consequences of Increasing Packing Length on the Dynamics of Polymer Melts > print |
| Home > Publications database > Consequences of Increasing Packing Length on the Dynamics of Polymer Melts > print |
| 001 | 276574 | ||
| 005 | 20240619091152.0 | ||
| 024 | 7 | _ | |a 10.1021/acs.macromol.5b00341 |2 doi |
| 024 | 7 | _ | |a 0024-9297 |2 ISSN |
| 024 | 7 | _ | |a 1520-5835 |2 ISSN |
| 024 | 7 | _ | |a WOS:000361935600031 |2 WOS |
| 024 | 7 | _ | |a altmetric:4936394 |2 altmetric |
| 037 | _ | _ | |a FZJ-2015-06939 |
| 041 | _ | _ | |a English |
| 082 | _ | _ | |a 540 |
| 100 | 1 | _ | |a Unidad, Herwin Jerome |0 P:(DE-Juel1)162191 |b 0 |e Corresponding author |
| 245 | _ | _ | |a Consequences of Increasing Packing Length on the Dynamics of Polymer Melts |
| 260 | _ | _ | |a Washington, DC |c 2015 |b Soc. |
| 336 | 7 | _ | |a Journal Article |b journal |m journal |0 PUB:(DE-HGF)16 |s 1448983254_13514 |2 PUB:(DE-HGF) |
| 336 | 7 | _ | |a Output Types/Journal article |2 DataCite |
| 336 | 7 | _ | |a Journal Article |0 0 |2 EndNote |
| 336 | 7 | _ | |a ARTICLE |2 BibTeX |
| 336 | 7 | _ | |a JOURNAL_ARTICLE |2 ORCID |
| 336 | 7 | _ | |a article |2 DRIVER |
| 520 | _ | _ | |a We revisit the nonuniversal aspect of polymer dynamics by considering both new and existing data on the zero-shear viscosity and linear viscoelastic response of various polymers, each with a wide range of molecular weights. Analysis of the zero-shear viscosity data in terms of the packing length p, whose role in entanglements has been discussed previously by Fetters and co-workers, reveals a behavior that is irreconcilable with our current understanding based on the tube model. Specifically, we find that the transition regime between Rouse and pure reptation dynamics, currently understood as the regime where contour length fluctuations are active, systematically shrinks as the packing length of the polymer increases. Further, we find that the slope of the loss moduli in the high-frequency wing of the terminal peak of well-entangled systems also decreases from the common −0.25 to −0.125 with increasing p. This is contrary to the single expected value of −0.25 from tube models which include contour length fluctuations or −0.5 from pure reptation. These findings hint on possible missing ingredients in our current understanding of polymer dynamics. |
| 536 | _ | _ | |a 6215 - Soft Matter, Health and Life Sciences (POF3-621) |0 G:(DE-HGF)POF3-6215 |c POF3-621 |f POF III |x 0 |
| 536 | _ | _ | |0 G:(DE-HGF)POF3-6G15 |f POF III |x 1 |c POF3-6G15 |a 6G15 - FRM II / MLZ (POF3-6G15) |
| 536 | _ | _ | |a 6G4 - Jülich Centre for Neutron Research (JCNS) (POF3-623) |0 G:(DE-HGF)POF3-6G4 |c POF3-623 |f POF III |x 2 |
| 588 | _ | _ | |a Dataset connected to CrossRef |
| 650 | 2 | 7 | |a Soft Condensed Matter |0 V:(DE-MLZ)SciArea-210 |2 V:(DE-HGF) |x 0 |
| 650 | 1 | 7 | |a Basic research |0 V:(DE-MLZ)GC-2004-2016 |2 V:(DE-HGF) |x 1 |
| 650 | 1 | 7 | |a Others |0 V:(DE-MLZ)GC-180 |2 V:(DE-HGF) |x 0 |
| 693 | _ | _ | |0 EXP:(DE-MLZ)NOSPEC-20140101 |5 EXP:(DE-MLZ)NOSPEC-20140101 |e No specific instrument |x 0 |
| 700 | 1 | _ | |a Goad, Mahmoud Abdel |0 P:(DE-HGF)0 |b 1 |
| 700 | 1 | _ | |a Bras, Ana |0 P:(DE-Juel1)140548 |b 2 |u fzj |
| 700 | 1 | _ | |a Zamponi, Michaela |0 P:(DE-Juel1)131056 |b 3 |u fzj |
| 700 | 1 | _ | |a Faust, Rudolf |0 P:(DE-HGF)0 |b 4 |
| 700 | 1 | _ | |a Allgaier, J. |0 P:(DE-Juel1)130501 |b 5 |
| 700 | 1 | _ | |a Pyckhout-Hintzen, Wim |0 P:(DE-Juel1)130902 |b 6 |u fzj |
| 700 | 1 | _ | |a Wischnewski, Andreas |0 P:(DE-Juel1)131040 |b 7 |u fzj |
| 700 | 1 | _ | |a Richter, Dieter |0 P:(DE-Juel1)130917 |b 8 |u fzj |
| 700 | 1 | _ | |a Fetters, Lewis J. |0 P:(DE-HGF)0 |b 9 |
| 773 | _ | _ | |a 10.1021/acs.macromol.5b00341 |g Vol. 48, no. 18, p. 6638 - 6645 |0 PERI:(DE-600)1491942-4 |n 18 |p 6638 - 6645 |t Macromolecules |v 48 |y 2015 |x 1520-5835 |
| 856 | 4 | _ | |u http://pubs.acs.org/doi/abs/10.1021/acs.macromol.5b00341 |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/276574/files/acs%252Emacromol%252E5b00341.pdf |y Restricted |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/276574/files/acs%252Emacromol%252E5b00341.gif?subformat=icon |x icon |y Restricted |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/276574/files/acs%252Emacromol%252E5b00341.jpg?subformat=icon-1440 |x icon-1440 |y Restricted |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/276574/files/acs%252Emacromol%252E5b00341.jpg?subformat=icon-180 |x icon-180 |y Restricted |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/276574/files/acs%252Emacromol%252E5b00341.jpg?subformat=icon-640 |x icon-640 |y Restricted |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/276574/files/acs%252Emacromol%252E5b00341.pdf?subformat=pdfa |x pdfa |y Restricted |
| 909 | C | O | |o oai:juser.fz-juelich.de:276574 |p VDB:MLZ |p VDB |
| 910 | 1 | _ | |a Forschungszentrum Jülich GmbH |0 I:(DE-588b)5008462-8 |k FZJ |b 0 |6 P:(DE-Juel1)162191 |
| 910 | 1 | _ | |a Forschungszentrum Jülich GmbH |0 I:(DE-588b)5008462-8 |k FZJ |b 2 |6 P:(DE-Juel1)140548 |
| 910 | 1 | _ | |a Forschungszentrum Jülich GmbH |0 I:(DE-588b)5008462-8 |k FZJ |b 3 |6 P:(DE-Juel1)131056 |
| 910 | 1 | _ | |a Forschungszentrum Jülich GmbH |0 I:(DE-588b)5008462-8 |k FZJ |b 5 |6 P:(DE-Juel1)130501 |
| 910 | 1 | _ | |a Forschungszentrum Jülich GmbH |0 I:(DE-588b)5008462-8 |k FZJ |b 6 |6 P:(DE-Juel1)130902 |
| 910 | 1 | _ | |a Forschungszentrum Jülich GmbH |0 I:(DE-588b)5008462-8 |k FZJ |b 7 |6 P:(DE-Juel1)131040 |
| 910 | 1 | _ | |a Forschungszentrum Jülich GmbH |0 I:(DE-588b)5008462-8 |k FZJ |b 8 |6 P:(DE-Juel1)130917 |
| 913 | 1 | _ | |a DE-HGF |b Forschungsbereich Materie |l Von Materie zu Materialien und Leben |1 G:(DE-HGF)POF3-620 |0 G:(DE-HGF)POF3-621 |2 G:(DE-HGF)POF3-600 |v In-house research on the structure, dynamics and function of matter |9 G:(DE-HGF)POF3-6215 |x 0 |4 G:(DE-HGF)POF |3 G:(DE-HGF)POF3 |
| 913 | 1 | _ | |a DE-HGF |9 G:(DE-HGF)POF3-6G15 |x 1 |4 G:(DE-HGF)POF |v FRM II / MLZ |1 G:(DE-HGF)POF3-6G0 |0 G:(DE-HGF)POF3-6G15 |3 G:(DE-HGF)POF3 |2 G:(DE-HGF)POF3-600 |b Forschungsbereich Materie |l Großgeräte: Materie |
| 913 | 1 | _ | |a DE-HGF |b Forschungsbereich Materie |l Von Materie zu Materialien und Leben |1 G:(DE-HGF)POF3-620 |0 G:(DE-HGF)POF3-623 |2 G:(DE-HGF)POF3-600 |v Facility topic: Neutrons for Research on Condensed Matter |9 G:(DE-HGF)POF3-6G4 |x 2 |4 G:(DE-HGF)POF |3 G:(DE-HGF)POF3 |
| 914 | 1 | _ | |y 2015 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0200 |2 StatID |b SCOPUS |
| 915 | _ | _ | |a JCR |0 StatID:(DE-HGF)0100 |2 StatID |b MACROMOLECULES : 2013 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0300 |2 StatID |b Medline |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0310 |2 StatID |b NCBI Molecular Biology Database |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0199 |2 StatID |b Thomson Reuters Master Journal List |
| 915 | _ | _ | |a WoS |0 StatID:(DE-HGF)0110 |2 StatID |b Science Citation Index |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0150 |2 StatID |b Web of Science Core Collection |
| 915 | _ | _ | |a WoS |0 StatID:(DE-HGF)0111 |2 StatID |b Science Citation Index Expanded |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)1150 |2 StatID |b Current Contents - Physical, Chemical and Earth Sciences |
| 915 | _ | _ | |a IF >= 5 |0 StatID:(DE-HGF)9905 |2 StatID |b MACROMOLECULES : 2013 |
| 920 | _ | _ | |l yes |
| 920 | 1 | _ | |0 I:(DE-Juel1)JCNS-FRM-II-20110218 |k JCNS (München) ; Jülich Centre for Neutron Science JCNS (München) ; JCNS-FRM-II |l JCNS-FRM-II |x 0 |
| 920 | 1 | _ | |0 I:(DE-Juel1)JCNS-1-20110106 |k Neutronenstreuung ; JCNS-1 |l Neutronenstreuung |x 1 |
| 980 | _ | _ | |a journal |
| 980 | _ | _ | |a VDB |
| 980 | _ | _ | |a I:(DE-Juel1)JCNS-FRM-II-20110218 |
| 980 | _ | _ | |a I:(DE-Juel1)JCNS-1-20110106 |
| 980 | _ | _ | |a UNRESTRICTED |
| Library | Collection | CLSMajor | CLSMinor | Language | Author |
|---|