% IMPORTANT: The following is UTF-8 encoded.  This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.

@ARTICLE{MalodeMolina:278935,
      author       = {Malo de Molina, Paula and Ihlefeldt, Franziska Stefanie and
                      Prévost, Sylvain and Herfurth, Christoph and Appavou,
                      Marie-Sousai and Laschewsky, André and Gradzielski,
                      Michael},
      title        = {{P}hase {B}ehavior of {N}onionic {M}icroemulsions with
                      {M}ulti-end-capped {P}olymers and {I}ts {R}elation to the
                      {M}esoscopic {S}tructure},
      journal      = {Langmuir},
      volume       = {31},
      number       = {18},
      issn         = {1520-5827},
      address      = {Washington, DC},
      publisher    = {ACS Publ.},
      reportid     = {FZJ-2015-07110},
      pages        = {5198 - 5209},
      year         = {2015},
      note         = {"final draft post referee" kann nicht beigebracht werden},
      abstract     = {The polymer architecture of telechelic or associative
                      polymers has a large impact on the bridging of
                      self-assembled structures. This work presents the phase
                      behavior, small angle neutron scattering (SANS), dynamic
                      light scattering (DLS), and fluorescence correlation
                      spectroscopy (FCS) of a nonionic oil-in-water (O/W)
                      microemulsion with hydrophobically end-capped multiarm
                      polymers with functionalities f = 2, 3, and 4. For high
                      polymer concentrations and large average interdroplet
                      distance relative to the end-to-end distance of the polymer,
                      d/Ree, the system phase separates into a dense, highly
                      connected droplet network phase, in equilibrium with a
                      dilute phase. The extent of the two-phase region is larger
                      for polymers with similar length but higher f. The
                      interaction potential between the droplets in the presence
                      of polymer has both a repulsive and an attractive
                      contribution as a result of the counterbalancing effects of
                      the exclusion by polymer chains and bridging between
                      droplets. This study experimentally demonstrates that higher
                      polymer functionalities induce a stronger attractive force
                      between droplets, which is responsible for a more extended
                      phase separation region, and correlate with lower collective
                      droplet diffusivities and higher amplitude of the second
                      relaxation time in DLS. The viscosity and the droplet
                      self-diffusion obtained from FCS, however, are dominated by
                      the end-capped chain concentration.},
      cin          = {JCNS (München) ; Jülich Centre for Neutron Science JCNS
                      (München) ; JCNS-FRM-II / Neutronenstreuung ; JCNS-1},
      ddc          = {670},
      cid          = {I:(DE-Juel1)JCNS-FRM-II-20110218 /
                      I:(DE-Juel1)JCNS-1-20110106},
      pnm          = {6G15 - FRM II / MLZ (POF3-6G15) / 6G4 - Jülich Centre for
                      Neutron Research (JCNS) (POF3-623)},
      pid          = {G:(DE-HGF)POF3-6G15 / G:(DE-HGF)POF3-6G4},
      experiment   = {EXP:(DE-MLZ)KWS1-20140101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000354578700023},
      doi          = {10.1021/acs.langmuir.5b00817},
      url          = {https://juser.fz-juelich.de/record/278935},
}