Hauptseite > Publikationsdatenbank > Clathrates of syndiotactic polystyrene (s-PS) and sulfonated s-PS with different guest molecules > print

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037 _ _ |a FZJ-2015-07171
041 _ _ |a English
100 1 _ |a Schiavone, Maria Maddalena
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111 2 _ |a 6th International Conference on Polymer Behaviour
|g I(CPB)6
|c Wien
|d 2014-09-22 - 2014-09-26
|w Austria
245 _ _ |a Clathrates of syndiotactic polystyrene (s-PS) and sulfonated s-PS with different guest molecules
260 _ _ |c 2014
336 7 _ |a Conference Presentation
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336 7 _ |a Conference Paper
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336 7 _ |a INPROCEEDINGS
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520 _ _ |a s-PS forms different co-crystals with several guest molecules[1] and so far different advanced materials[2] have been produced starting from s-PS co-crystalline films. To study the introduction of bulky molecules into s-PS lattice using guest exchange phenomenon we conducted a series of small angle neutron scattering experiments on s-PS clathrates with poly(ethylene-glycol)-dimethyl-ethers as guests with different molecular weight, by using the difference in scattering-length density between protonated and deuterated isotopologues.Furthermore, as sulfonated s-PS can be used as proton exchange membrane for fuel cells, we approached a structural study of these materials by preparing films of sulfonated s-PS co-crystals through a post-polymerization modification. The first results on two subjects will be presented.[1]. Chatani et al. Polymer, 1993, 34, 1620.[2]. Guerra et al. Journal of Polymer Science Part B, Polymer Physics, 2012, 50, 305.
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693 _ _ |a Forschungs-Neutronenquelle Heinz Maier-Leibnitz
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