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@ARTICLE{Betzinger:279143,
author = {Betzinger, Markus and Friedrich, Christoph and Görling,
Andreas and Blügel, Stefan},
title = {{P}recise all-electron dynamical response functions:
{A}pplication to {COHSEX} and the {RPA} correlation energy},
journal = {Physical review / B},
volume = {92},
number = {24},
issn = {1098-0121},
address = {College Park, Md.},
publisher = {APS},
reportid = {FZJ-2015-07222},
pages = {245101},
year = {2015},
abstract = {We present a methodology to calculate frequency and
momentum dependent all-electron response functions
determined within Kohn-Sham density functional theory. It
overcomes the main obstacle in calculating response
functions in practice, which is the slow convergence with
respect to the number of unoccupied states and the basis-set
size. In this approach, the usual sum-over-states expression
of perturbation theory is complemented by the response of
the orbital basis functions, explicitly constructed by
radial integrations of frequency-dependent Sternheimer
equations. To an essential extent an infinite number of
unoccupied states are included in this way. Furthermore, the
response of the core electrons is treated virtually exactly,
which is out of reach otherwise. The method is an extension
of the recently introduced incomplete-basis-set correction
(IBC) [Betzinger et al., Phys. Rev. B 85, 245124 (2012);
Phys. Rev. B 88, 075130 (2013)] to the frequency and
momentum domain. We have implemented the generalized IBC
within the all-electron full-potential linearized
augmented-plane-wave method and demonstrate for rocksalt BaO
the improved convergence of the dynamical Kohn-Sham
polarizability. We apply this technique to compute (a)
quasiparticle energies employing the COHSEX approximation
for the self-energy of many-body perturbation theory and (b)
all-electron RPA correlation energies. It is shown that the
favorable convergence of the polarizability is passed over
to the COHSEX and RPA calculation.},
cin = {IAS-1 / PGI-1 / JARA-FIT},
ddc = {530},
cid = {I:(DE-Juel1)IAS-1-20090406 / I:(DE-Juel1)PGI-1-20110106 /
$I:(DE-82)080009_20140620$},
pnm = {142 - Controlling Spin-Based Phenomena (POF3-142) / 143 -
Controlling Configuration-Based Phenomena (POF3-143)},
pid = {G:(DE-HGF)POF3-142 / G:(DE-HGF)POF3-143},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000365774100001},
doi = {10.1103/PhysRevB.92.245101},
url = {https://juser.fz-juelich.de/record/279143},
}