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@ARTICLE{Menzel:279252,
author = {Menzel, Stephan and Kaupmann, Philip and Waser, R.},
title = {{U}nderstanding filamentary growth in electrochemical
metallization memory cells using kinetic {M}onte {C}arlo
simulations},
journal = {Nanoscale},
volume = {7},
number = {29},
issn = {2040-3372},
address = {Cambridge},
publisher = {RSC Publ.},
reportid = {FZJ-2015-07267},
pages = {12673 - 12681},
year = {2015},
abstract = {We report on a 2D kinetic Monte Carlo model that describes
the resistive switching in electrochemical metallization
cells. To simulate the switching process, we consider
several different processes on the atomic scale:
electron-transfer reactions at the boundaries, ion
migration, adsorption/desorption from/to interfaces, surface
diffusion and nucleation. These processes result in a
growth/dissolution of a metallic filament within an
insulating matrix. In addition, the model includes electron
tunneling between the growing filament and the counter
electrode, which allows for simulating multilevel switching.
It is shown that the simulation model can reproduce the
reported switching kinetics, switching variability and
multilevel capabilities of ECM devices. As a major result,
the influence of mechanical stress working on the host
matrix due to the filamentary growth is investigated. It is
demonstrated that the size and shape of the filament depend
on the Young's modulus of the insulating matrix. For high
values a wire-like structure evolves, whereas the shape is
dendritic if the Young's modulus is negligible.},
cin = {PGI-7},
ddc = {600},
cid = {I:(DE-Juel1)PGI-7-20110106},
pnm = {521 - Controlling Electron Charge-Based Phenomena
(POF3-521)},
pid = {G:(DE-HGF)POF3-521},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000358207700052},
doi = {10.1039/C5NR02258D},
url = {https://juser.fz-juelich.de/record/279252},
}