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@ARTICLE{Niewolak:279586,
      author       = {Niewolak, Leszek and Zurek, Joanna and Menzler, Norbert H.
                      and Grüner, Daniel and Quadakkers, Willem J.},
      title        = {{O}xidation and {R}eduction {K}inetics of {I}ron and {I}ron
                      {B}ased {A}lloys {U}sed as {S}torage {M}aterials in {H}igh
                      {T}emperature {B}attery},
      journal      = {Materials at high temperatures},
      volume       = {32},
      number       = {1-2},
      issn         = {0960-3409},
      address      = {Amsterdam [u.a.]},
      publisher    = {Elsevier Science},
      reportid     = {FZJ-2015-07470},
      pages        = {81-91},
      year         = {2015},
      abstract     = {The background of the present studies relates to the
                      development of a novel high temperature energy storage
                      system based on a solid oxide cell. The energy is stored in
                      a metal/metal oxide system which is part of the fuel side of
                      the cell. The aim of the present study was to evaluate the
                      suitability of pure iron and iron based model alloys as
                      possible energy storage material for this type of high
                      temperature battery system at a service temperature of
                      800°C. For this purpose the oxidation and reduction
                      behaviour of iron in Ar–H2–(H2O) environments has been
                      examined. The reduction process in $Ar–2\%H2$ of the
                      wüstite scale formed on pure iron in Ar–H2–H2O was
                      hampered by the formation of a continuous, gas tight
                      metallic iron layer on its surface. Possible approaches to
                      increase oxidation and reduction kinetics by optimised alloy
                      compositions for the Fe storage are discussed.},
      cin          = {IEK-2 / IEK-1},
      ddc          = {620},
      cid          = {I:(DE-Juel1)IEK-2-20101013 / I:(DE-Juel1)IEK-1-20101013},
      pnm          = {111 - Efficient and Flexible Power Plants (POF3-111)},
      pid          = {G:(DE-HGF)POF3-111},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000348713300013},
      doi          = {10.1179/0960340914Z.00000000080},
      url          = {https://juser.fz-juelich.de/record/279586},
}