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@ARTICLE{Skaja:279651,
author = {Skaja, Katharina and Bäumer, Christoph and Peters, Oliver
and Menzel, Stephan and Moors, Marco and Du, Hongchu and
Bornhöfft, Manuel and Schmitz, Christoph and Feyer, Vitaliy
and Jia, Chun-Lin and Schneider, Claus Michael and Mayer,
Joachim and Waser, Rainer and Dittmann, Regina},
title = {{A}valanche-{D}ischarge-{I}nduced {E}lectrical {F}orming in
{T}antalum {O}xide-{B}ased {M}etal-{I}nsulator-{M}etal
{S}tructures},
journal = {Advanced functional materials},
volume = {25},
number = {46},
issn = {1616-301X},
address = {Weinheim},
publisher = {Wiley-VCH},
reportid = {FZJ-2015-07533},
pages = {7154–7162},
year = {2015},
abstract = {Oxide-based metal–insulator–metal structures are of
special interest for future resistive random-access
memories. In such cells, redox processes on the nanoscale
occur during resistive switching, which are initiated by the
reversible movement of native donors, such as oxygen
vacancies. The formation of these filaments is mainly
attributed to an enhanced oxygen diffusion due to Joule
heating in an electric field or due to electrical breakdown.
Here, the development of a dendrite-like structure, which is
induced by an avalanche discharge between the top electrode
and the Ta2O5-x layer, is presented, which occurs instead of
a local breakdown between top and bottom electrode. The
dendrite-like structure evolves primarily at structures with
a pronounced interface adsorbate layer. Furthermore, local
conductive atomic force microscopy reveals that the entire
dendrite region becomes conductive. Via spectromicroscopy it
is demonstrated that the subsequent switching is caused by a
valence change between Ta4+ and Ta5+, which takes place over
the entire former Pt/Ta2O5-x interface of the dendrite-like
structure.},
cin = {PGI-7 / PGI-5 / PGI-6},
ddc = {620},
cid = {I:(DE-Juel1)PGI-7-20110106 / I:(DE-Juel1)PGI-5-20110106 /
I:(DE-Juel1)PGI-6-20110106},
pnm = {521 - Controlling Electron Charge-Based Phenomena
(POF3-521)},
pid = {G:(DE-HGF)POF3-521},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000366503700005},
doi = {10.1002/adfm.201502767},
url = {https://juser.fz-juelich.de/record/279651},
}