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001     279906
005     20210129221155.0
024 7 _ |a 10.1002/pssb.201552138
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024 7 _ |a 0370-1972
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100 1 _ |a Rushchanskii, Konstantin
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245 _ _ |a Ferroelectricity in (PbySn1−y)2P2S6 mixed crystals and random field BEG model
260 _ _ |a Weinheim
|c 2016
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|c 2015-10-19
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|c 2016-02-01
264 _ 1 |3 print
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336 7 _ |a Journal Article
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520 _ _ |a In Sninline imagePinline imageSinline image ferroelectric under compression, the second-order phase transition line is observed down to the tricritical point as the transition temperature decreases to 250 K. A tricriticality at a similar temperature is also revealed in the mixed crystals on Sinline imageSe substitution. For the mixed crystals with Sninline imagePb substitution, ultrasound, hypersound, and low-frequency dielectric studies also show heterophase features appearing on decrease of the ferroelectric transition temperature below a so-called “waterline temperature” near 250 K. Such behavior agrees with the Blume–Emery–Griffiths (BEG) model appropriate for the ferroelectric system under investigation with a three-well local potential for the order parameter fluctuations. The BEG model modified by the random-field phase diagram in the vicinity of the tricritical point qualitatively explains the influence of the cationic substitution on the (Pbinline imageSninline image)inline imagePinline imageSinline image ferroelectric properties.
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542 _ _ |i 2015-10-19
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700 1 _ |a Bilanych, R. M.
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700 1 _ |a Molnar, A. A.
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700 1 _ |a Yevych, R. M.
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700 1 _ |a Kohutych, A. A.
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700 1 _ |a Perechinskii, S. I.
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700 1 _ |a Samulionis, V.
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700 1 _ |a Banys, J.
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700 1 _ |a Vysochanskii, Y. M.
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