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@ARTICLE{Ringe:280299,
      author       = {Ringe, Emilie and DeSantis, Christopher J. and Collins,
                      Sean M. and Duchamp, Martial and Dunin-Borkowski, Rafal and
                      Skrabalak, Sara E. and Midgley, Paul A.},
      title        = {{R}esonances of nanoparticles with poor plasmonic metal
                      tips},
      journal      = {Scientific reports},
      volume       = {5},
      issn         = {2045-2322},
      address      = {London},
      publisher    = {Nature Publishing Group},
      reportid     = {FZJ-2016-00088},
      pages        = {17431 -},
      year         = {2015},
      abstract     = {The catalytic and optical properties of metal nanoparticles
                      can be combined to create platforms for light-driven
                      chemical energy storage and enhanced in-situ reaction
                      monitoring. However, the heavily damped plasmon resonances
                      of many catalytically active metals (e.g. Pt, Pd) prevent
                      this dual functionality in pure nanostructures. The addition
                      of catalytic metals at the surface of efficient plasmonic
                      particles thus presents a unique opportunity if the
                      resonances can be conserved after coating. Here, nanometer
                      resolution electron-based techniques (electron energy loss,
                      cathodoluminescence, and energy dispersive X-ray
                      spectroscopy) are used to show that Au particles
                      incorporating a catalytically active but heavily damped
                      metal, Pd, sustain multiple size-dependent localized surface
                      plasmon resonances (LSPRs) that are narrow and strongly
                      localized at the Pd-rich tips. The resonances also couple
                      with a dielectric substrate and other nanoparticles,
                      establishing that the full range of plasmonic behavior is
                      observed in these multifunctional nanostructures despite the
                      presence of Pd.},
      cin          = {PGI-5},
      ddc          = {000},
      cid          = {I:(DE-Juel1)PGI-5-20110106},
      pnm          = {143 - Controlling Configuration-Based Phenomena (POF3-143)},
      pid          = {G:(DE-HGF)POF3-143},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000365417900006},
      pubmed       = {pmid:26617270},
      doi          = {10.1038/srep17431},
      url          = {https://juser.fz-juelich.de/record/280299},
}