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@ARTICLE{Collins:280304,
author = {Collins, Sean M. and Ringe, Emilie and Duchamp, Martial and
Saghi, Zineb and Dunin-Borkowski, Rafal and Midgley, Paul
A.},
title = {{E}igenmode {T}omography of {S}urface {C}harge
{O}scillations of {P}lasmonic {N}anoparticles by {E}lectron
{E}nergy {L}oss {S}pectroscopy},
journal = {ACS photonics},
volume = {2},
number = {11},
issn = {2330-4022},
address = {Washington, DC},
publisher = {ACS},
reportid = {FZJ-2016-00093},
pages = {1628 - 1635},
year = {2015},
abstract = {Plasmonic devices designed in three dimensions enable
careful tuning of optical responses for control of complex
electromagnetic interactions on the nanoscale. Probing the
fundamental characteristics of the constituent nanoparticle
building blocks is, however, often constrained by
diffraction-limited spatial resolution in optical
spectroscopy. Electron microscopy techniques, including
electron energy loss spectroscopy (EELS), have recently been
developed to image surface plasmon resonances qualitatively
at the nanoscale in three dimensions using tomographic
reconstruction techniques. Here, we present an experimental
realization of a distinct method that uses direct analysis
of modal surface charge distributions to reconstruct
quantitatively the three-dimensional eigenmodes of a silver
right bipyramid on a metal oxide substrate. This eigenmode
tomography removes ambiguity in two-dimensional imaging of
spatially localized plasmonic resonances, reveals
substrate-induced mode degeneracy breaking in the bipyramid,
and enables EELS for the analysis not of a particular
electron-induced response but of the underlying geometric
modes characteristic of particle surface plasmons.},
cin = {PGI-5},
ddc = {620},
cid = {I:(DE-Juel1)PGI-5-20110106},
pnm = {143 - Controlling Configuration-Based Phenomena (POF3-143)},
pid = {G:(DE-HGF)POF3-143},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000365148400016},
doi = {10.1021/acsphotonics.5b00421},
url = {https://juser.fz-juelich.de/record/280304},
}