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@ARTICLE{Klobes:280353,
author = {Klobes, Benedikt and Hu, Michael Y. and Beekman, Matt and
Johnson, David C. and Hermann, Raphael},
title = {{C}onfined lattice dynamics of single and quadruple
{S}n{S}e bilayers in [({S}n{S}e) $_{1.04}$ ] $_{m}$
[{M}o{S}e $_{2}$ ] $_{n}$ ferecrystals},
journal = {Nanoscale},
volume = {8},
number = {2},
issn = {2040-3372},
address = {Cambridge},
publisher = {RSC Publ.},
reportid = {FZJ-2016-00137},
pages = {856 - 861},
year = {2016},
abstract = {The Sn specific densities of phonon states in the SnSe
subunits of [(SnSe)1.04]m[MoSe2]n ferecrystals with (m,n) =
(1,1), (4,1) and in bulk SnSe were derived from nuclear
inelastic scattering by the 119Sn Mössbauer resonance.
Using different measurement configurations, phonons with
polarization parallel and perpendicular to the ferecrystal
plane were specifically probed. Vibrational properties and
phonon spectral weight are found to strongly depend on the
phonon polarization and layer count m. A highly peculiar
feature of these ferecrystal densities of phonon states is
the emergence of rather sharp high energy vibrational modes
polarized perpendicular to the ferecrystal plane, which
contrasts with usual findings in thin layered structures and
nanostructured materials in general, and a depletion of
modes with a gap appearing between acoustic and high energy
modes. The spectral weight of these phonons depends on the
overall SnSe content, m, but cannot be unambiguously
attributed to SnSe–MoSe2 interfaces. Considering the low
energy part of lattice dynamics, ferecrystals exhibit rather
low average phonon group velocities as compared to the speed
of sound in the long wavelength limit. For the (1,1)
ferecrystal, this effect is most pronounced for vibrations
polarized in the ferecrystal plane. Thus, an experimental
microscopic origin for the vibrational and bonding
anisotropy in subunits of ferecrystals is provided.},
cin = {JCNS-2 / PGI-4 / JARA-FIT},
ddc = {600},
cid = {I:(DE-Juel1)JCNS-2-20110106 / I:(DE-Juel1)PGI-4-20110106 /
$I:(DE-82)080009_20140620$},
pnm = {144 - Controlling Collective States (POF3-144) / 524 -
Controlling Collective States (POF3-524) / 6212 - Quantum
Condensed Matter: Magnetism, Superconductivity (POF3-621) /
6213 - Materials and Processes for Energy and Transport
Technologies (POF3-621) / 6G4 - Jülich Centre for Neutron
Research (JCNS) (POF3-623)},
pid = {G:(DE-HGF)POF3-144 / G:(DE-HGF)POF3-524 /
G:(DE-HGF)POF3-6212 / G:(DE-HGF)POF3-6213 /
G:(DE-HGF)POF3-6G4},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000367258500021},
pubmed = {pmid:26647996},
doi = {10.1039/C5NR06138E},
url = {https://juser.fz-juelich.de/record/280353},
}