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@ARTICLE{Lasri:280354,
author = {Lasri, Karima and Mahmoud, Abdelfattah and Saadoune, Ismael
and Sougrati, Moulay Tahar and Stievano, Lorenzo and
Lippens, Pierre-Emmanuel and Ehrenberg, Helmut and Hermann,
Raphael},
title = {{T}oward understanding the lithiation/delithiation process
in {F}e0.5{T}i{OPO}4/{C} electrode material for lithium-ion
batteries},
journal = {Solar energy materials $\&$ solar cells},
volume = {148},
issn = {0927-0248},
address = {Amsterdam},
publisher = {North Holland},
reportid = {FZJ-2016-00138},
pages = {11-19},
year = {2016},
abstract = {Fe0.5TiOPO4/C composite was used as anode material for LIB
and exhibits excellent cycling performance when the
electrode is cycled in two different voltage ranges
[3.0–1.3 V] and [3.0–0.02 V] where different insertion
mechanisms were involved. A detailed in situ XANES
spectroscopy study coupled to the electrochemical analyses,
clearly established that the structure of Fe0.5TiOPO4/C
electrode materials is preserved when cycled between 3.0 and
1.3 V. Furthermore, a formation of new phase at the end of
first discharge was evidenced, with a reversible capacity of
100 mA h g−1 after 50 cycles at C/5 rate. At highly
lithiated states, [3.0–0.02 V] voltage range, a
reduction-decomposition reaction highlights the
Li-insertion/extraction behaviors, and low phase
crystallinity is observed during cycling, in addition an
excellent rate behavior and a reversible capacity of 250 mA
h g−1 can still be maintained after 50 cycles at high
cycling rate 5C.},
cin = {JCNS-2 / PGI-4 / JARA-FIT},
ddc = {530},
cid = {I:(DE-Juel1)JCNS-2-20110106 / I:(DE-Juel1)PGI-4-20110106 /
$I:(DE-82)080009_20140620$},
pnm = {144 - Controlling Collective States (POF3-144) / 524 -
Controlling Collective States (POF3-524) / 6212 - Quantum
Condensed Matter: Magnetism, Superconductivity (POF3-621) /
6213 - Materials and Processes for Energy and Transport
Technologies (POF3-621) / 6G4 - Jülich Centre for Neutron
Research (JCNS) (POF3-623)},
pid = {G:(DE-HGF)POF3-144 / G:(DE-HGF)POF3-524 /
G:(DE-HGF)POF3-6212 / G:(DE-HGF)POF3-6213 /
G:(DE-HGF)POF3-6G4},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000371944500003},
doi = {10.1016/j.solmat.2015.11.021},
url = {https://juser.fz-juelich.de/record/280354},
}