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| 100 | 1 | _ | |a Kang, Kyongok |0 P:(DE-Juel1)130749 |b 0 |e Corresponding author |u fzj |
| 245 | _ | _ | |a Charged Colloidal Rods Out of Equilibrium |
| 260 | _ | _ | |a Irvine, Calif. |c 2015 |b Scientific Research Publ. |
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| 520 | _ | _ | |a This article is a comprehensive overview of the ongoing research of the author on charged colloid- al rods out of equilibrium, under external electric fields and at high concentrations around the glass transition. The suspensions of fd-virus particles are used as a model system for charged col- loidal rods, which exhibit several disorder-order (and liquid-crystalline) phase transitions. When a low AC electric field is applied to suspensions in isotropic-nematic coexistence concentration, with frequencies that are sufficiently low to polarize the electric double layer and the layer of condensed ions, various phases/states are induced: a chiral nematic, a dynamical state where ne- matic domains persistently melt and form, and a uniform homeotropic phase. A point in the field-amplitude versus frequency diagram, where various transitions lines meet, can be identified as a non-equilibrium critical point. Without an electric field, at high concentrations of charged fd-rods, various self-assembled orientation textures are found beyond the isotropic-nematic coex- istence regions, and a glass transition is observed on approach and within the glass state that are probed. The presented system exhibits transient behaviors of repulsive glasses and slow dynamics out of equilibrium. |
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