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@ARTICLE{Davaasuren:280531,
author = {Davaasuren, Bambar and Dashjav, Enkhtsetseg and Kreiner,
Guido and Borrmann, Horst and Weber, Sven-Ulf and Becker,
Klaus-Dieter and Jochen Litterst, Fred and Kniep, Rüdiger},
title = {{C}rystal structure and {M}össbauer studies of the
isotypic {F}e$_{6}$-cluster compounds
{RE}$_{15}$[{F}e$_{8}${C}$_{25}$], {RE}={D}y, {H}o},
journal = {Journal of solid state chemistry},
volume = {225},
issn = {0022-4596},
address = {Orlando, Fla.},
publisher = {Academic Press},
reportid = {FZJ-2016-00299},
pages = {450 - 454},
year = {2015},
abstract = {The carboferrates RE15[Fe8C25] (RE=Dy, Ho) were prepared
from mixtures of the elements by arc-melting followed with
subsequent annealing at 1373 K. The crystal structures were
determined from single crystal X-ray diffraction data and
revealed an isotypic relationship to Er15[Fe8C25] (hP48,
P321). The main feature of the crystal structure is given by
Fe6 cluster units characterized by covalent Fe–Fe bonding
interactions. 57Fe Mössbauer spectra of Dy15[Fe8C25] were
fitted by three subspectra with relative spectral weights of
about 3:3:2 which is in general agreement with the crystal
structure. Below 50 K, an onset of magnetic hyperfine fields
at the three iron sites is observed which is supposed to be
caused by dipolar fields arising from neighboring, slowly
relaxing Dy magnetic moments.},
cin = {IEK-1},
ddc = {540},
cid = {I:(DE-Juel1)IEK-1-20101013},
pnm = {131 - Electrochemical Storage (POF3-131)},
pid = {G:(DE-HGF)POF3-131},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000352828000063},
doi = {10.1016/j.jssc.2015.01.019},
url = {https://juser.fz-juelich.de/record/280531},
}