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@ARTICLE{Ramasamy:280576,
      author       = {Ramasamy, Madhumidha and Baumann, Stefan and Palisaitis,
                      Justinas and Schulze-Küppers, Falk and Balaguer, Maria and
                      Kim, Daejin and Meulenberg, Wilhelm A. and Mayer, Joachim
                      and Bhave, Ramesh and Guillon, Olivier and Bram, Martin},
      title        = {{I}nfluence of {M}icrostructure and {S}urface {A}ctivation
                      of {D}ual-{P}hase {M}embrane {C}e 0.8 {G}d 0.2 {O} 2−δ
                      -{F}e{C}o 2 {O} 4 on {O}xygen {P}ermeation},
      journal      = {Journal of the American Ceramic Society},
      volume       = {99},
      number       = {1},
      issn         = {0002-7820},
      address      = {Oxford [u.a.]},
      publisher    = {Wiley-Blackwell},
      reportid     = {FZJ-2016-00344},
      pages        = {349 - 355},
      year         = {2016},
      abstract     = {Dual-phase oxygen transport membranes are fast-growing
                      research interest for application in oxyfuel combustion
                      process. One such potential candidate is CGO-FCO (60 $wt\%$
                      Ce0.8Gd0.2O2−δ–40 $wt\%$ FeCo2O4) identified to provide
                      good oxygen permeation flux with substantial stability in
                      harsh atmosphere. Dense CGO-FCO membranes of 1 mm thickness
                      were fabricated by sintering dry pellets pressed from
                      powders synthesized by one-pot method (modified Pechini
                      process) at 1200°C for 10 h. Microstructure analysis
                      indicates presence of a third orthorhombic perovskite phase
                      in the sintered composite. It was also identified that the
                      spinel phase tends to form an oxygen deficient phase at the
                      grain boundary of spinel and CGO phases. Surface exchange
                      limitation of the membranes was overcome by
                      La0.6Sr0.4Co0.2Fe0.8O3−δ (LSCF) porous layer coating over
                      the composite. The oxygen permeation flux of the CGO-FCO
                      screen printed with a porous layer of 10 μm thick LSCF is
                      0.11 mL/cm2 per minute at 850°C with argon as sweep and air
                      as feed gas at the rates of 50 and 250 mL/min.},
      cin          = {IEK-1 / JARA-ENERGY},
      ddc          = {660},
      cid          = {I:(DE-Juel1)IEK-1-20101013 / $I:(DE-82)080011_20140620$},
      pnm          = {113 - Methods and Concepts for Material Development
                      (POF3-113) / GREEN-CC - Graded Membranes for Energy
                      Efficient New Generation Carbon Capture Process (608524) /
                      HITEC - Helmholtz Interdisciplinary Doctoral Training in
                      Energy and Climate Research (HITEC) (HITEC-20170406)},
      pid          = {G:(DE-HGF)POF3-113 / G:(EU-Grant)608524 /
                      G:(DE-Juel1)HITEC-20170406},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000368076800050},
      doi          = {10.1111/jace.13938},
      url          = {https://juser.fz-juelich.de/record/280576},
}