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000280613 0247_ $$2doi$$a10.1088/0953-8984/28/3/035401
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000280613 1001_ $$0P:(DE-HGF)0$$aGrzechnik, A.$$b0$$eCorresponding author
000280613 245__ $$aPressure-induced non-superconducting phase of β -Na 0.33 V 2 O 5 and the mechanism of high-pressure phase transitions in β -Na 0.33 V 2 O 5 and β -Li 0.33 V 2 O 5 at room temperature
000280613 260__ $$aBristol$$bIOP Publ.$$c2016
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000280613 520__ $$aThe crystal structure of β-Na0.33V2O5 (C2/m, Z  =  6) has been studied on compression to 19 GPa at room temperature using synchrotron single-crystal diffraction in a diamond anvil cell. The vanadate bronze undergoes a phase transition to a non-superconducting phase at about 12 GPa due to changes of polyhedral connectivities in the vanadate framework and due to ordering of the Na+ cations. This novel structure (Cm, Z  =  6) is interpreted as an intermediate stage in the sequence of pressure-induced transformations in the β-A 0.33V2O5 bronzes (A: Li, Na) at room temperature. This study reveals the close relation between the loss of the two-leg ladder V–V system and non-superconducting state of the β-A 0.33V2O5 materials.
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000280613 7001_ $$0P:(DE-HGF)0$$aUeda, Y.$$b1
000280613 7001_ $$0P:(DE-HGF)0$$aYamauchi, T.$$b2
000280613 7001_ $$0P:(DE-HGF)0$$aHanfland, M.$$b3
000280613 7001_ $$0P:(DE-Juel1)156570$$aHering, P.$$b4
000280613 7001_ $$0P:(DE-Juel1)157928$$aPotapkin, V.$$b5
000280613 7001_ $$0P:(DE-Juel1)145694$$aFriese, K.$$b6
000280613 773__ $$0PERI:(DE-600)1472968-4$$a10.1088/0953-8984/28/3/035401$$gVol. 28, no. 3, p. 035401 -$$n3$$p035401 -$$tJournal of physics / Condensed matter$$v28$$x1361-648X$$y2016
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