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| 100 | 1 | _ | |a Grzechnik, A. |0 P:(DE-HGF)0 |b 0 |e Corresponding author |
| 245 | _ | _ | |a Pressure-induced non-superconducting phase of β -Na 0.33 V 2 O 5 and the mechanism of high-pressure phase transitions in β -Na 0.33 V 2 O 5 and β -Li 0.33 V 2 O 5 at room temperature |
| 260 | _ | _ | |a Bristol |c 2016 |b IOP Publ. |
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| 520 | _ | _ | |a The crystal structure of β-Na0.33V2O5 (C2/m, Z = 6) has been studied on compression to 19 GPa at room temperature using synchrotron single-crystal diffraction in a diamond anvil cell. The vanadate bronze undergoes a phase transition to a non-superconducting phase at about 12 GPa due to changes of polyhedral connectivities in the vanadate framework and due to ordering of the Na+ cations. This novel structure (Cm, Z = 6) is interpreted as an intermediate stage in the sequence of pressure-induced transformations in the β-A 0.33V2O5 bronzes (A: Li, Na) at room temperature. This study reveals the close relation between the loss of the two-leg ladder V–V system and non-superconducting state of the β-A 0.33V2O5 materials. |
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| 773 | _ | _ | |a 10.1088/0953-8984/28/3/035401 |g Vol. 28, no. 3, p. 035401 - |0 PERI:(DE-600)1472968-4 |n 3 |p 035401 - |t Journal of physics / Condensed matter |v 28 |y 2016 |x 1361-648X |
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