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@ARTICLE{Adelsberger:280652,
      author       = {Adelsberger, Joseph and Bivigou-Koumba, Achille M. and
                      Miasnikova, Anna and Busch, Peter and Laschewsky, André and
                      Müller-Buschbaum, Peter and Papadakis, Christine M.},
      title        = {{P}olystyrene-block-poly (methoxy diethylene glycol
                      acrylate)-block-polystyrene triblock copolymers in aqueous
                      solution—a {SANS} study of the temperature-induced
                      switching behavior},
      journal      = {Colloid $\&$ polymer science},
      volume       = {293},
      number       = {5},
      issn         = {1435-1536},
      address      = {Berlin},
      publisher    = {Springer},
      reportid     = {FZJ-2016-00416},
      pages        = {1515 - 1523},
      year         = {2015},
      note         = {FINAL DRAFT POST REFEREE wird nicht zur Verfügung
                      gestellt. Mic, 15.01.2016},
      abstract     = {A concentrated solution of a symmetric triblock copolymer
                      with a thermoresponsive poly(methoxy diethylene glycol
                      acrylate) (PMDEGA) middle block and short hydrophobic, fully
                      deuterated polystyrene end blocks is investigated in D2O
                      where it undergoes a lower critical solution
                      temperature-type phase transition at ca. 36 °C. Small-angle
                      neutron scattering (SANS) in a wide temperature range
                      (15–50 °C) is used to characterize the size and inner
                      structure of the micelles as well as the correlation between
                      the micelles and the formation of aggregates by the micelles
                      above the cloud point (CP). A model featuring spherical
                      core-shell micelles, which are correlated by a hard-sphere
                      potential or a sticky hard-sphere potential together with a
                      Guinier form factor describing aggregates formed by the
                      micelles above the CP, fits the SANS curves well in the
                      entire temperature range. The thickness of the
                      thermoresponsive micellar PMDEGA shell as well as the
                      hard-sphere radius increase slightly already below the cloud
                      point. Whereas the thickness of the thermoresponsive
                      micellar shell hardly shrinks when heating through the CP
                      and up to 50 °C, the hard-sphere radius decreases within
                      3.5 K at the CP. The volume fraction decreases already
                      significantly below the CP, which may be at the origin of
                      the previously observed gel–sol transition far below the
                      CP (Miasnikova et al., Langmuir 28: 4479–4490, 2012).
                      Above the CP, small, and at higher temperatures, large
                      aggregates are formed by the micelles.},
      cin          = {JCNS (München) ; Jülich Centre for Neutron Science JCNS
                      (München) ; JCNS-FRM-II},
      ddc          = {540},
      cid          = {I:(DE-Juel1)JCNS-FRM-II-20110218},
      pnm          = {6G15 - FRM II / MLZ (POF3-6G15) / 6G4 - Jülich Centre for
                      Neutron Research (JCNS) (POF3-623)},
      pid          = {G:(DE-HGF)POF3-6G15 / G:(DE-HGF)POF3-6G4},
      experiment   = {EXP:(DE-MLZ)KWS2-20140101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000353348000021},
      doi          = {10.1007/s00396-015-3535-6},
      url          = {https://juser.fz-juelich.de/record/280652},
}