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@ARTICLE{Kubacki:280884,
author = {Kubacki, Jerzy and Kajewski, Dariusz and Koehl, Annemarie
and Lenser, Christian and Dittmann, Regina and Szade, Jacek},
title = {{X}-ray absorption and resonant photoemission studies of
electroforming process in {F}e-doped {S}r{T}i{O} 3 epitaxial
films},
journal = {X-ray spectrometry},
volume = {44},
number = {5},
issn = {0049-8246},
address = {New York, NY [u.a.]},
publisher = {Wiley},
reportid = {FZJ-2016-00595},
pages = {339 - 343},
year = {2015},
abstract = {This work presents the results of the electronic structure
investigations of epitaxial $2\%$ Fe-doped SrTiO3 film. The
electroforming process of the film was performed inside the
ultra-high vacuum test chamber by applying positive 10 V
bias to the film with the use of the aluminium ‘brush’
electrode. The X-ray absorption and resonant photoemission
methods were used to study the effect of Fe doping and
electroformation on the electronic structure of the SrTiO3
films. Analysis of the valence band revealed the increase of
the photoelectron intensity in the band gap region as the
result of Fe doping. Electroformation caused a slight
variation of the iron originating electronic states derived
from the resonant photoemission, which can probably be
related to the increasing contribution from the Fe2+ ions
with respect to the Fe3+ ones. The titanium partial density
of states showed an increase in the band gap region after
the electroformation process. The significant decreases of
the iron concentration derived from the photoemission
spectra were found after electroforming procedure. The
observed changes can be related to the increased migration
of oxygen and possibly also iron ions provoked by a strong
electric field applied by the electrode, eventually leading
to modification of the local electronic structure.},
cin = {PGI-7},
ddc = {530},
cid = {I:(DE-Juel1)PGI-7-20110106},
pnm = {521 - Controlling Electron Charge-Based Phenomena
(POF3-521)},
pid = {G:(DE-HGF)POF3-521},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000360088600005},
doi = {10.1002/xrs.2637},
url = {https://juser.fz-juelich.de/record/280884},
}