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000280899 1001_ $$0P:(DE-HGF)0$$aBick, D. S.$$b0
000280899 245__ $$aPr x Ba 1-x CoO 3 Oxide Electrodes for Oxygen Evolution Reaction in Alkaline Solutions by Chemical Solution Deposition
000280899 260__ $$aPennington, NJ$$bElectrochemical Soc.$$c2016
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000280899 520__ $$aPerovskite PrxBa1-xCoO3 (PBCO) thin film electrodes were used in a water splitting electrolysis cell for oxygen evolution reaction (OER) and studied by cyclic voltammetry. We systematically varied the composition of the PBCO deposited by spin-coating using different Ba to Pr ratios. The influence of Pr-content in the perovskite on catalytic OER activity is discussed for two different substrates, namely platinized Si and laser polished Ti. The crystallographic structure of the thin films and the oxidation state of the metal ions in the perovskite is examined by XRD and X-ray photoelectron spectroscopy, respectively. In addition, we propose a laser-polishing process of the Ti substrates as alternative to the classical surface treatment, providing smooth and homogeneous surfaces. Accelerated life time tests have shown the advantage of the catalytically active films deposited on laser polished Ti substrates. 
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000280899 7001_ $$0P:(DE-HGF)0$$aGriesche, J. D.$$b1
000280899 7001_ $$0P:(DE-HGF)0$$aSchneller, T.$$b2
000280899 7001_ $$0P:(DE-Juel1)130982$$aStaikov, G.$$b3
000280899 7001_ $$0P:(DE-Juel1)131022$$aWaser, R.$$b4
000280899 7001_ $$0P:(DE-Juel1)131014$$aValov, I.$$b5$$eCorresponding author
000280899 773__ $$0PERI:(DE-600)2002179-3$$a10.1149/2.0311603jes$$gVol. 163, no. 3, p. F166 - F170$$n3$$pF166 - F170$$tJournal of the Electrochemical Society$$v163$$x1945-7111$$y2016
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