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@ARTICLE{Bick:280899,
author = {Bick, D. S. and Griesche, J. D. and Schneller, T. and
Staikov, G. and Waser, R. and Valov, I.},
title = {{P}r x {B}a 1-x {C}o{O} 3 {O}xide {E}lectrodes for {O}xygen
{E}volution {R}eaction in {A}lkaline {S}olutions by
{C}hemical {S}olution {D}eposition},
journal = {Journal of the Electrochemical Society},
volume = {163},
number = {3},
issn = {1945-7111},
address = {Pennington, NJ},
publisher = {Electrochemical Soc.},
reportid = {FZJ-2016-00610},
pages = {F166 - F170},
year = {2016},
abstract = {Perovskite PrxBa1-xCoO3 (PBCO) thin film electrodes were
used in a water splitting electrolysis cell for oxygen
evolution reaction (OER) and studied by cyclic voltammetry.
We systematically varied the composition of the PBCO
deposited by spin-coating using different Ba to Pr ratios.
The influence of Pr-content in the perovskite on catalytic
OER activity is discussed for two different substrates,
namely platinized Si and laser polished Ti. The
crystallographic structure of the thin films and the
oxidation state of the metal ions in the perovskite is
examined by XRD and X-ray photoelectron spectroscopy,
respectively. In addition, we propose a laser-polishing
process of the Ti substrates as alternative to the classical
surface treatment, providing smooth and homogeneous
surfaces. Accelerated life time tests have shown the
advantage of the catalytically active films deposited on
laser polished Ti substrates.},
cin = {PGI-7},
ddc = {540},
cid = {I:(DE-Juel1)PGI-7-20110106},
pnm = {521 - Controlling Electron Charge-Based Phenomena
(POF3-521)},
pid = {G:(DE-HGF)POF3-521},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000370861500092},
doi = {10.1149/2.0311603jes},
url = {https://juser.fz-juelich.de/record/280899},
}