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@ARTICLE{Navarro:280913,
      author       = {Navarro, P. and Bocquet, F. C. and Deperasińska, I. and
                      Pirug, G. and Tautz, F. S. and Orrit, M.},
      title        = {{E}lectron {E}nergy {L}oss of {T}errylene {D}eposited on
                      {A}u(111): {V}ibrational and {E}lectronic {S}pectroscopy},
      journal      = {The journal of physical chemistry / C},
      volume       = {119},
      number       = {1},
      issn         = {1932-7455},
      address      = {Washington, DC},
      publisher    = {Soc.},
      reportid     = {FZJ-2016-00624},
      pages        = {277 - 283},
      year         = {2015},
      abstract     = {We have investigated the vibrational and electronic
                      properties of terrylene by high-resolution electron
                      energy-loss spectroscopy (HREELS), Fourier-transform
                      infrared spectroscopy, and low-temperature single-molecule
                      fluorescence spectroscopy. Terrylene thin films were
                      sublimated in an ultrahigh vacuum on the Au(111) surface in
                      order to record the HREEL spectra. Polycrystalline
                      p-dichlorobenzene was used as a matrix to isolate a single
                      terrylene molecule at 1.5 K and record its fluorescence
                      spectrum. The infrared spectrum, the vibrational components
                      from the fluorescence spectrum, and density functional
                      theory calculations were used for the assignment and
                      identification of the active modes found in HREELS. Finally,
                      we report a loss signal around 17 000 cm–1 (2.1 eV) for
                      the first singlet electronic excited state in agreement with
                      optical spectroscopy. The HREEL spectra show both IR- and
                      Raman-active vibration modes because of specific surface
                      selection rules. Energy-loss spectroscopy could be used as a
                      complementary technique to explore some other degrees of
                      freedom that are not accessible by optical means.},
      cin          = {PGI-3 / JARA-FIT},
      ddc          = {540},
      cid          = {I:(DE-Juel1)PGI-3-20110106 / $I:(DE-82)080009_20140620$},
      pnm          = {141 - Controlling Electron Charge-Based Phenomena
                      (POF3-141)},
      pid          = {G:(DE-HGF)POF3-141},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000347744700031},
      doi          = {10.1021/jp5086262},
      url          = {https://juser.fz-juelich.de/record/280913},
}