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@ARTICLE{Krupski:280969,
author = {Krupski, Katarzyna and Moors, Marco and Jóźwik, Paweł
and Kobiela, Tomasz and Krupski, Aleksander},
title = {{S}tructure {D}etermination of {A}u on {P}t(111) {S}urface:
{LEED}, {STM} and {DFT} {S}tudy},
journal = {Materials},
volume = {8},
number = {6},
issn = {1996-1944},
address = {Basel},
publisher = {MDPI},
reportid = {FZJ-2016-00680},
pages = {2935 - 2952},
year = {2015},
abstract = {Low-energy electron diffraction (LEED), scanning tunneling
microscopy (STM) and density functional theory (DFT)
calculations have been used to investigate the atomic and
electronic structure of gold deposited (between 0.8 and 1.0
monolayer) on the Pt(111) face in ultrahigh vacuum at room
temperature. The analysis of LEED and STM measurements
indicates two-dimensional growth of the first Au monolayer.
Change of the measured surface lattice constant equal to
2.80 Å after Au adsorption was not observed. Based on DFT,
the distance between the nearest atoms in the case of bare
Pt(111) and Au/Pt(111) surface is equal to 2.83 Å, which
gives $1\%$ difference in comparison with STM values. The
first and second interlayer spacing of the clean Pt(111)
surface are expanded by $+0.87\%$ and contracted by
$−0.43\%,$ respectively. The adsorption energy of the Au
atom on the Pt(111) surface is dependent on the adsorption
position, and there is a preference for a hollow fcc site.
For the Au/Pt(111) surface, the top interlayer spacing is
expanded by $+2.16\%$ with respect to the ideal bulk value.
Changes in the electronic properties of the Au/Pt(111)
system below the Fermi level connected to the interaction of
Au atoms with Pt(111) surface are observed.},
cin = {PGI-7},
ddc = {600},
cid = {I:(DE-Juel1)PGI-7-20110106},
pnm = {521 - Controlling Electron Charge-Based Phenomena
(POF3-521)},
pid = {G:(DE-HGF)POF3-521},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000357588900007},
doi = {10.3390/ma8062935},
url = {https://juser.fz-juelich.de/record/280969},
}