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000281044 1001_ $$0P:(DE-HGF)0$$aHuttmann, Felix$$b0$$eCorresponding author
000281044 245__ $$aTuning the van der Waals Interaction of Graphene with Molecules via Doping
000281044 260__ $$aCollege Park, Md.$$bAPS$$c2015
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000281044 520__ $$aWe use scanning tunneling microscopy to visualize and thermal desorption spectroscopy to quantitatively measure that the binding of naphthalene molecules to graphene, a case of pure van der Waals interaction, strengthens with n and weakens with p doping of graphene. Density-functional theory calculations that include the van der Waals interaction in a seamless, ab initio way accurately reproduce the observed trend in binding energies. Based on a model calculation, we propose that the van der Waals interaction is modified by changing the spatial extent of graphene’s π orbitals via doping.
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000281044 7001_ $$0P:(DE-HGF)0$$aMartínez-Galera, Antonio J.$$b1
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000281044 7001_ $$0P:(DE-Juel1)130513$$aAtodiresei, Nicolae$$b3$$ufzj
000281044 7001_ $$0P:(DE-HGF)0$$aSchumacher, Stefan$$b4
000281044 7001_ $$0P:(DE-HGF)0$$aStandop, Sebastian$$b5
000281044 7001_ $$0P:(DE-HGF)0$$aHamada, Ikutaro$$b6
000281044 7001_ $$0P:(DE-HGF)0$$aWehling, Tim O.$$b7
000281044 7001_ $$0P:(DE-Juel1)130548$$aBlügel, Stefan$$b8$$ufzj
000281044 7001_ $$0P:(DE-HGF)0$$aMichely, Thomas$$b9
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