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@ARTICLE{Bnting:281503,
author = {Bünting, Aiko and Uhlenbruck, Sven and Sebold, Doris and
Buchkremer, H. P. and Vassen, Robert},
title = {{T}hree-{D}imensional, {F}ibrous {L}ithium {I}ron
{P}hosphate {S}tructures {D}eposited by {M}agnetron
{S}puttering},
journal = {ACS applied materials $\&$ interfaces},
volume = {7},
number = {40},
issn = {1944-8252},
address = {Washington, DC},
reportid = {FZJ-2016-01196},
pages = {22594 - 22600},
year = {2015},
abstract = {Crystalline, three-dimensional (3D) structured lithium iron
phosphate (LiFePO4) thin films with additional carbon are
fabricated by a radio frequency (RF) magnetron-sputtering
process in a single step. The 3D structured thin films are
obtained at deposition temperatures of 600 °C and
deposition times longer than 60 min by using a conventional
sputtering setup. In contrast to glancing angle deposition
(GLAD) techniques, no tilting of the substrate is required.
Thin films are characterized by X-ray diffraction (XRD),
Raman spectrospcopy, scanning electron microscopy (SEM),
cyclic voltammetry (CV), and galvanostatic charging and
discharging. The structured LiFePO4 + C thin films consist
of fibers that grow perpendicular to the substrate surface.
The fibers have diameters up to 500 nm and crystallize in
the desired olivine structure. The 3D structured thin films
have superior electrochemical properties compared with dense
two-dimensional (2D) LiFePO4 thin films and are, hence, very
promising for application in 3D microbatteries.},
cin = {IEK-1},
ddc = {540},
cid = {I:(DE-Juel1)IEK-1-20101013},
pnm = {131 - Electrochemical Storage (POF3-131) / HITEC -
Helmholtz Interdisciplinary Doctoral Training in Energy and
Climate Research (HITEC) (HITEC-20170406)},
pid = {G:(DE-HGF)POF3-131 / G:(DE-Juel1)HITEC-20170406},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000363001500057},
pubmed = {pmid:26381359},
doi = {10.1021/acsami.5b07090},
url = {https://juser.fz-juelich.de/record/281503},
}