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@ARTICLE{Li:281786,
author = {Li, Dongjiang and Danilov, Dmitri L. and Xie, Jie and
Raijmakers, Luc and Gao, Lu and Yang, Yong and Notten, Peter
H. L.},
title = {{D}egradation {M}echanisms of {C}6/{L}i{F}e{PO}4
{B}atteries: {E}xperimental {A}nalyses of {C}alendar
{A}ging},
journal = {Electrochimica acta},
volume = {190},
issn = {0013-4686},
address = {New York, NY [u.a.]},
publisher = {Elsevier},
reportid = {FZJ-2016-01455},
pages = {1124 - 1133},
year = {2016},
abstract = {The capacity loss and material decay of C6/LiFePO4 (LFP)
batteries have been investigated under various storage
conditions in dependence of State-of-Charge (SoC) and
temperature. The electromotive force (EMF) curves, which are
regularly determined by mathematical extrapolation of the
measured voltage discharge curves, are used to investigate
the aging mechanisms during storage. The irreversible
capacity loss, which is accurately determined on the basis
of the maximum storage capacity estimated from the EMF
curves, increases as a function of temperature and SoC. The
cyclable Li-ion loss during storage is considered to be the
main source of the irreversible capacity loss. Strikingly,
the inaccessibility of graphite is observed during storage
at 60 °C. The graphite capacity decay has been
quantitatively determined by non-destructive analyses on the
basis of dVEMF/dQ curves. Deposition of Fe on the graphite
electrode has experimentally been confirmed by X-ray
photoelectron spectroscopy (XPS). The increasing graphite
inaccessibility is shown to be the consequence of Fe
dissolution from the cathode and the subsequent deposition
onto the anode.},
cin = {IEK-9},
ddc = {540},
cid = {I:(DE-Juel1)IEK-9-20110218},
pnm = {131 - Electrochemical Storage (POF3-131)},
pid = {G:(DE-HGF)POF3-131},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000371141500133},
doi = {10.1016/j.electacta.2015.12.161},
url = {https://juser.fz-juelich.de/record/281786},
}