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| Home > Publications database > Growth of high quality single crystals of strontium doped (Nd,Pr)-nickelates, Nd $_{2−x}$ Sr $_{x}$ NiO $_{4+δ}$ and Pr $_{2−x}$ Sr $_{x}$ NiO $_{4+δ}$ > print |
| Home > Publications database > Growth of high quality single crystals of strontium doped (Nd,Pr)-nickelates, Nd $_{2−x}$ Sr $_{x}$ NiO $_{4+δ}$ and Pr $_{2−x}$ Sr $_{x}$ NiO $_{4+δ}$ > print |
| 001 | 282889 | ||
| 005 | 20210129222145.0 | ||
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| 100 | 1 | _ | |0 P:(DE-HGF)0 |a Wahyudi, O. |b 0 |
| 245 | _ | _ | |a Growth of high quality single crystals of strontium doped (Nd,Pr)-nickelates, Nd $_{2−x}$ Sr $_{x}$ NiO $_{4+δ}$ and Pr $_{2−x}$ Sr $_{x}$ NiO $_{4+δ}$ |
| 260 | _ | _ | |a London |b RSC |c 2015 |
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| 520 | _ | _ | |a Large size and high quality single crystals of Nd2−xSrxNiO4+δ and Pr2−xSrxNiO4+δ, with selected composition (x = 0.0, 0.1 and 0.5), were grown by a floating-zone technique using an image furnace. We found that even small deviations from the ideal cation stoichiometry led to either NiO segregation or formation of Ni-poor Pr4Ni3O10−x, or RExOy intergrowth phases, rendering the title compounds unstable even under ambient conditions. Related to potential applications as membranes in SOFC, we importantly found Nd2−xSrxNiO4+δ and Pr2−xSrxNiO4+δ powders, obtained from ground stoichiometric single crystals, to be stable in air at high temperature (1000 °C), contrary to the partial decomposition observed when synthesized as polycrystalline powders by classical solid state synthesis. The presence of NiO/Pr4Ni3O10−x or RExOy intergrowth phases are discussed as a drawback limiting high temperature stability for Pr2NiO4+δ. Grown single crystals were characterised by neutron and X-ray diffraction as well as by electron microscopy (SEM/EDS), revealing their excellent quality in terms of composition, homogeneity and crystallinity. For each crystal, the oxygen content was determined by thermogravimetric analysis in a reductive atmosphere. Transmission electron microscopy highlighted a complex incommensurate structure for Pr2NiO4.25 and Nd2NiO4.25 with a 2D modulation vector related to oxygen ordering. |
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| 700 | 1 | _ | |0 P:(DE-HGF)0 |a Ceretti, M. |b 1 |e Corresponding author |
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