001     282893
005     20240712112816.0
024 7 _ |a 10.3390/c2010004
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024 7 _ |a 2128/9875
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037 _ _ |a FZJ-2016-01638
041 _ _ |a English
082 _ _ |a 570
100 1 _ |a Flegler, Andreas
|0 P:(DE-HGF)0
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|e Corresponding author
245 _ _ |a Manganese Oxide Coated Carbon Materials as Hybrid Catalysts for the Application in Primary Aqueous Metal-Air Batteries
260 _ _ |a Basel
|c 2016
|b MDPI
336 7 _ |a Journal Article
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336 7 _ |a article
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500 _ _ |a Missing Journal: C (C) = 2311-5629 (import from CrossRef)
520 _ _ |a One of the major challenges of metal-air batteries is the impeded oxygen reduction reaction (ORR) during discharge occurring at the gas diffusion electrode (GDE) of the battery. Due to the impeded ORR, high overpotentials emerge and result in a loss of energy efficiency. In order to improve the latter, suitable catalysts have to be employed. Transition metal oxides like manganese oxides (e.g., MnO2, Mn2O3, Mn3O4, Mn5O8, MnOOH) [1,2] are known as good and inexpensive materials for the ORR in alkaline media. A drawback of manganese oxide catalysts is the poor electrical conductivity. Hence, the approach presented in this work aims to enhance the catalytic activity of Mn3O4 and γ–MnO2 by the incorporation of conductive carbon material into the pure manganese oxide. The resulting hybrid catalysts are prepared either by impregnation of Super C 65, Vulcan XC 72, and Kuraray YP 50F via a sol-gel technique employing a MnO2 precursor sol or by direct precipitation of Mn3O4 or γ–MnO2 particles in the presence of the carbon materials mentioned above. Investigations by rotating disc electrode (RDE) show a noticeably higher catalytic activity of the hybrid catalysts than for the pure materials. For verification of the results measured by RDE, screen printed GDEs are prepared and tested in Zn-air full cells.
536 _ _ |a 131 - Electrochemical Storage (POF3-131)
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536 _ _ |0 G:(DE-Juel1)HITEC-20170406
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|a HITEC - Helmholtz Interdisciplinary Doctoral Training in Energy and Climate Research (HITEC) (HITEC-20170406)
588 _ _ |a Dataset connected to CrossRef
700 1 _ |a Hartmann, Sarah
|0 P:(DE-HGF)0
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700 1 _ |a Weinrich, Henning
|0 P:(DE-Juel1)164223
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700 1 _ |a Kapuschinski, Martina
|0 P:(DE-HGF)0
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700 1 _ |a Settelein, Jochen
|0 P:(DE-HGF)0
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700 1 _ |a Lorrmann, Henning
|0 P:(DE-HGF)0
|b 5
700 1 _ |a Sextl, Gerhard
|0 P:(DE-HGF)0
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773 _ _ |a 10.3390/c2010004
|g Vol. 2, no. 1, p. 4 -
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|t C – journal of carbon research
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|x 2313-0105
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910 1 _ |a Forschungszentrum Jülich GmbH
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