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@ARTICLE{Klobes:283031,
author = {Klobes, B. and Arinicheva, Y. and Neumeier, S. and Simon,
R. E. and Jafari, A. and Bosbach, D. and Hermann, R. P.},
title = {{Q}uadrupole splitting and {E}u partial lattice dynamics in
europium orthophosphate {E}u{PO} 4},
journal = {Hyperfine interactions},
volume = {237},
number = {1},
issn = {1572-9540},
address = {Dordrecht [u.a.]},
publisher = {Springer Science + Business Media B.V},
reportid = {FZJ-2016-01713},
pages = {31},
year = {2016},
abstract = {Hyperfine interactions in europium orthophosphate EuPO4
were investigated using 151Eu Mössbauer spectroscopy from 6
to 300 K. The value of the quadrupole splitting and the
asymmetry parameter were refined and further substantiated
by nuclear forward scattering data obtained at room
temperature. The temperature dependence of the relative
absorption was modeled with an Eu specific Debye temperature
of 221(1) K. Eu partial lattice dynamics were probed by
means of nuclear inelastic scattering and the mean force
constant, the Lamb-Mössbauer factor, the internal energy,
the vibrational entropy, the average phonon group velocity
were calculated using the extracted density of phonon
states. In general, Eu specific vibrations are characterized
by rather small phonon energies and contribute strongly to
the total entropy of the system. Although there is no
classical Debye like behavior at low vibrational energies,
the average phonon group velocity can be reasonably
approximated using a linear fit.},
cin = {IEK-6 / JCNS-2 / PGI-4 / JARA-FIT},
ddc = {530},
cid = {I:(DE-Juel1)IEK-6-20101013 / I:(DE-Juel1)JCNS-2-20110106 /
I:(DE-Juel1)PGI-4-20110106 / $I:(DE-82)080009_20140620$},
pnm = {161 - Nuclear Waste Management (POF3-161) / 144 -
Controlling Collective States (POF3-144) / 524 - Controlling
Collective States (POF3-524) / 6212 - Quantum Condensed
Matter: Magnetism, Superconductivity (POF3-621) / 6213 -
Materials and Processes for Energy and Transport
Technologies (POF3-621) / 6G4 - Jülich Centre for Neutron
Research (JCNS) (POF3-623) / HITEC - Helmholtz
Interdisciplinary Doctoral Training in Energy and Climate
Research (HITEC) (HITEC-20170406)},
pid = {G:(DE-HGF)POF3-161 / G:(DE-HGF)POF3-144 /
G:(DE-HGF)POF3-524 / G:(DE-HGF)POF3-6212 /
G:(DE-HGF)POF3-6213 / G:(DE-HGF)POF3-6G4 /
G:(DE-Juel1)HITEC-20170406},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000372730100004},
doi = {10.1007/s10751-016-1211-y},
url = {https://juser.fz-juelich.de/record/283031},
}