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@ARTICLE{Becker:283530,
      author       = {Becker, Jan Philipp and Urbain, Félix and Smirnov,
                      Vladimir and Rau, Uwe and Ziegler, Jürgen and Kaiser,
                      Bernhard and Jaegermann, Wolfram and Finger, Friedhelm},
      title        = {{M}odeling and practical realization of thin film
                      silicon-based integrated solar water splitting devices},
      journal      = {Physica status solidi / A},
      volume       = {213},
      number       = {7},
      issn         = {0031-8965},
      address      = {Weinheim},
      publisher    = {Wiley-VCH},
      reportid     = {FZJ-2016-01849},
      pages        = {1738 - 1746},
      year         = {2016},
      abstract     = {An integrated solar water splitting device based on thin
                      film silicon multijunction photocathodes is presented. A
                      graphical representation of the photovoltaic
                      current–voltage data is introduced which allows for an
                      estimation of the maximum achievable solar-to-hydrogen
                      efficiency of the integrated device. Furthermore, a simple
                      yet very useful series circuit model is used to predict the
                      photoelectrochemical performance of the integrated device in
                      a more elaborate way when the j–V characteristics of the
                      individual components are known. Within the model, the j–V
                      characteristics of each component can be either modeled with
                      parameters from the literature or measured. The
                      photocathode, the electrolyte concentration, and the
                      hydrogen and oxygen evolving catalysts were varied
                      exemplarily and the impact of each component on the
                      integrated device performance was evaluated. A maximum
                      solar-to-hydrogen efficiency of $9.5\%$ was found using a
                      triple junction solar cell functionalized with a Pt catalyst
                      for the hydrogen evolution and a RuO2 catalyst for the
                      oxygen evolution reaction in a 1 M KOH electrolyte. This
                      result was confirmed experimentally and is compared to
                      efficiencies reported in the literature.},
      cin          = {IEK-5},
      ddc          = {530},
      cid          = {I:(DE-Juel1)IEK-5-20101013},
      pnm          = {126 - Solar Fuels (POF3-126) / 121 - Solar cells of the
                      next generation (POF3-121) / HITEC - Helmholtz
                      Interdisciplinary Doctoral Training in Energy and Climate
                      Research (HITEC) (HITEC-20170406)},
      pid          = {G:(DE-HGF)POF3-126 / G:(DE-HGF)POF3-121 /
                      G:(DE-Juel1)HITEC-20170406},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000385222900013},
      doi          = {10.1002/pssa.201533025},
      url          = {https://juser.fz-juelich.de/record/283530},
}