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@ARTICLE{Wischnewski:28406,
author = {Wischnewski, A. and Monkenbusch, M. and Willner, L. and
Richter, D. and Kali, G.},
title = {{D}irect observation of the transition from free to
constrained single-segment motion in entangled polymer
melts},
journal = {Physical review letters},
volume = {90},
issn = {0031-9007},
address = {College Park, Md.},
publisher = {APS},
reportid = {PreJuSER-28406},
pages = {058302},
year = {2003},
note = {Record converted from VDB: 12.11.2012},
abstract = {We report a direct determination of the time dependent
mean-squared segment displacement of a polymer chain in the
melt covering the transition from free to constraint Rouse
relaxation along the virtual tube of the reptation model.
This has been achieved by a neutron spin-echo (NSE)
measurement of the segmental self-correlation function as
conveyed by the spin-incoherent scattering from two fully
protonated polymer melts, polyethylene and polyethylene
propylene. Within the scenario of de Gennes reptation model
a transition of the time dependence of segmental
mean-squared displacements from proportional tot(1/2) to
proportional tot(1/4) is expected and clearly corroborated
by the incoherent NSE results.},
keywords = {J (WoSType)},
cin = {IFF-NST},
ddc = {550},
cid = {I:(DE-Juel1)VDB34},
pnm = {Kondensierte Materie},
pid = {G:(DE-Juel1)FUEK242},
shelfmark = {Physics, Multidisciplinary},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000180918300062},
doi = {10.1103/PhysRevLett.90.058302},
url = {https://juser.fz-juelich.de/record/28406},
}