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@ARTICLE{Ibach:28617,
author = {Ibach, H. and Giesen, M. and Schmickler, W.},
title = {{P}otential dependence of the step line tension on surfaces
in contact with an electrolyte},
journal = {Journal of electroanalytical chemistry},
volume = {544},
issn = {0022-0728},
address = {New York, NY [u.a.]},
publisher = {Elsevier},
reportid = {PreJuSER-28617},
pages = {13 - 23},
year = {2003},
note = {Record converted from VDB: 12.11.2012},
abstract = {The potential dependence of the step line tension for
electrodes in contact with an electrolyte, but without
specific adsorption, is calculated by solving the
Poisson-Boltzmann equation numerically. Two contributions to
the potential dependence are found. A contribution arising
from the step geometry is zero at the potential of zero
charge (pzc) and positive for either sign of the potential.
The prevailing contribution arises from the dipole moment of
the charge distribution at steps. It is approximately
proportional to the dipole moment and the specific surface
charge, and negative for potentials positive of pzc. (C)
2003 Published by Elsevier Science B.V.},
keywords = {J (WoSType)},
cin = {ISG-3 / ISG-4},
ddc = {540},
cid = {I:(DE-Juel1)VDB43 / I:(DE-Juel1)VDB44},
pnm = {Kondensierte Materie},
pid = {G:(DE-Juel1)FUEK242},
shelfmark = {Chemistry, Analytical / Electrochemistry},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000181648700002},
doi = {10.1016/S0022-0728(03)00055-X},
url = {https://juser.fz-juelich.de/record/28617},
}