Home > Publications database > Potential dependence of the step line tension on surfaces in contact with an electrolyte > print |
001 | 28617 | ||
005 | 20200402210453.0 | ||
024 | 7 | _ | |2 DOI |a 10.1016/S0022-0728(03)00055-X |
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037 | _ | _ | |a PreJuSER-28617 |
041 | _ | _ | |a eng |
082 | _ | _ | |a 540 |
084 | _ | _ | |2 WoS |a Chemistry, Analytical |
084 | _ | _ | |2 WoS |a Electrochemistry |
100 | 1 | _ | |a Ibach, H. |b 0 |u FZJ |0 P:(DE-Juel1)VDB5414 |
245 | _ | _ | |a Potential dependence of the step line tension on surfaces in contact with an electrolyte |
260 | _ | _ | |a New York, NY [u.a.] |b Elsevier |c 2003 |
300 | _ | _ | |a 13 - 23 |
336 | 7 | _ | |a Journal Article |0 PUB:(DE-HGF)16 |2 PUB:(DE-HGF) |
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336 | 7 | _ | |a Journal Article |0 0 |2 EndNote |
336 | 7 | _ | |a ARTICLE |2 BibTeX |
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336 | 7 | _ | |a article |2 DRIVER |
440 | _ | 0 | |a Journal of Electroanalytical Chemistry |x 0022-0728 |0 3261 |v 544 |
500 | _ | _ | |a Record converted from VDB: 12.11.2012 |
520 | _ | _ | |a The potential dependence of the step line tension for electrodes in contact with an electrolyte, but without specific adsorption, is calculated by solving the Poisson-Boltzmann equation numerically. Two contributions to the potential dependence are found. A contribution arising from the step geometry is zero at the potential of zero charge (pzc) and positive for either sign of the potential. The prevailing contribution arises from the dipole moment of the charge distribution at steps. It is approximately proportional to the dipole moment and the specific surface charge, and negative for potentials positive of pzc. (C) 2003 Published by Elsevier Science B.V. |
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588 | _ | _ | |a Dataset connected to Web of Science |
650 | _ | 7 | |a J |2 WoSType |
653 | 2 | 0 | |2 Author |a single-crystal electrode |
653 | 2 | 0 | |2 Author |a capacitance |
653 | 2 | 0 | |2 Author |a double layer |
653 | 2 | 0 | |2 Author |a interfacial structure |
653 | 2 | 0 | |2 Author |a tension |
653 | 2 | 0 | |2 Author |a theory |
700 | 1 | _ | |a Giesen, M. |b 1 |u FZJ |0 P:(DE-Juel1)4744 |
700 | 1 | _ | |a Schmickler, W. |b 2 |0 P:(DE-HGF)0 |
773 | _ | _ | |a 10.1016/S0022-0728(03)00055-X |g Vol. 544, p. 13 - 23 |p 13 - 23 |q 544<13 - 23 |0 PERI:(DE-600)1491150-4 |t Journal of electroanalytical chemistry |v 544 |y 2003 |x 0022-0728 |
856 | 7 | _ | |u http://dx.doi.org/10.1016/S0022-0728(03)00055-X |
909 | C | O | |o oai:juser.fz-juelich.de:28617 |p VDB |
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914 | 1 | _ | |y 2003 |
915 | _ | _ | |0 StatID:(DE-HGF)0010 |a JCR/ISI refereed |
920 | 1 | _ | |k ISG-3 |l Institut für Grenzflächen und Vakuumtechnologien |d 31.12.2006 |g ISG |0 I:(DE-Juel1)VDB43 |x 0 |
920 | 1 | _ | |k ISG-4 |l Institut für biologisch-anorganische Grenzflächen |d 31.12.2001 |g ISG |0 I:(DE-Juel1)VDB44 |x 1 |
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981 | _ | _ | |a I:(DE-Juel1)PGI-3-20110106 |
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