001     28617
005     20200402210453.0
024 7 _ |2 DOI
|a 10.1016/S0022-0728(03)00055-X
024 7 _ |2 WOS
|a WOS:000181648700002
037 _ _ |a PreJuSER-28617
041 _ _ |a eng
082 _ _ |a 540
084 _ _ |2 WoS
|a Chemistry, Analytical
084 _ _ |2 WoS
|a Electrochemistry
100 1 _ |a Ibach, H.
|b 0
|u FZJ
|0 P:(DE-Juel1)VDB5414
245 _ _ |a Potential dependence of the step line tension on surfaces in contact with an electrolyte
260 _ _ |a New York, NY [u.a.]
|b Elsevier
|c 2003
300 _ _ |a 13 - 23
336 7 _ |a Journal Article
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336 7 _ |a Journal Article
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336 7 _ |a ARTICLE
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336 7 _ |a JOURNAL_ARTICLE
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336 7 _ |a article
|2 DRIVER
440 _ 0 |a Journal of Electroanalytical Chemistry
|x 0022-0728
|0 3261
|v 544
500 _ _ |a Record converted from VDB: 12.11.2012
520 _ _ |a The potential dependence of the step line tension for electrodes in contact with an electrolyte, but without specific adsorption, is calculated by solving the Poisson-Boltzmann equation numerically. Two contributions to the potential dependence are found. A contribution arising from the step geometry is zero at the potential of zero charge (pzc) and positive for either sign of the potential. The prevailing contribution arises from the dipole moment of the charge distribution at steps. It is approximately proportional to the dipole moment and the specific surface charge, and negative for potentials positive of pzc. (C) 2003 Published by Elsevier Science B.V.
536 _ _ |a Kondensierte Materie
|c M02
|2 G:(DE-HGF)
|0 G:(DE-Juel1)FUEK242
|x 0
588 _ _ |a Dataset connected to Web of Science
650 _ 7 |a J
|2 WoSType
653 2 0 |2 Author
|a single-crystal electrode
653 2 0 |2 Author
|a capacitance
653 2 0 |2 Author
|a double layer
653 2 0 |2 Author
|a interfacial structure
653 2 0 |2 Author
|a tension
653 2 0 |2 Author
|a theory
700 1 _ |a Giesen, M.
|b 1
|u FZJ
|0 P:(DE-Juel1)4744
700 1 _ |a Schmickler, W.
|b 2
|0 P:(DE-HGF)0
773 _ _ |a 10.1016/S0022-0728(03)00055-X
|g Vol. 544, p. 13 - 23
|p 13 - 23
|q 544<13 - 23
|0 PERI:(DE-600)1491150-4
|t Journal of electroanalytical chemistry
|v 544
|y 2003
|x 0022-0728
856 7 _ |u http://dx.doi.org/10.1016/S0022-0728(03)00055-X
909 C O |o oai:juser.fz-juelich.de:28617
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|v Kondensierte Materie
|l Kondensierte Materie
|b Materie
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914 1 _ |y 2003
915 _ _ |0 StatID:(DE-HGF)0010
|a JCR/ISI refereed
920 1 _ |k ISG-3
|l Institut für Grenzflächen und Vakuumtechnologien
|d 31.12.2006
|g ISG
|0 I:(DE-Juel1)VDB43
|x 0
920 1 _ |k ISG-4
|l Institut für biologisch-anorganische Grenzflächen
|d 31.12.2001
|g ISG
|0 I:(DE-Juel1)VDB44
|x 1
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981 _ _ |a I:(DE-Juel1)PGI-3-20110106
981 _ _ |a I:(DE-Juel1)ICS-7-20110106


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