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000029433 084__ $$2WoS$$aChemistry, Physical
000029433 084__ $$2WoS$$aPhysics, Condensed Matter
000029433 1001_ $$0P:(DE-Juel1)VDB3067$$aSchober, T.$$b0$$uFZJ
000029433 245__ $$aTubular high-temperature proton conductors : transport numbers and hydrogen injection
000029433 260__ $$aAmsterdam [u.a.]$$bElsevier Science$$c2001
000029433 300__ $$a95 - 104
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000029433 440_0 $$05565$$aSolid State Ionics$$v139$$x0167-2738
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000029433 520__ $$aTubes of high-temperature proton conductors [Sr(Zr0.8Ce0.2)(0.8)In0.2O3-x, BaZr0.9Y0.1O3-x and CaZr0.9In0.1O3-x] were investigated in various gas atmospheres. Transport numbers for selected species were measured and compared with literature values. The electrochemical injection of hydrogen into inert gases was demonstrated. By increasing the proton current, titration curves were obtained analogous to those for strong acid-strong base titrations. The modelling of such curves is presented. Fuel cell operation and steam electrolysis was also demonstrated. Exposure of one side of the tubes to ethanol vapor was found to lead to proton pick-up of the tubes. More drastic effects were observed with acetone vapor, which also produced proton pick-up but also the deposition of undesirable carbonaceous layers. (C) 2001 Elsevier Science B.V. All rights reserved.
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000029433 65320 $$2Author$$aproton conduction
000029433 65320 $$2Author$$ahydrogen pumping
000029433 65320 $$2Author$$aperovskite
000029433 65320 $$2Author$$asteam electrolysis
000029433 65320 $$2Author$$atransport numbers
000029433 773__ $$0PERI:(DE-600)1500750-9$$a10.1016/S0167-2738(00)00822-5$$gVol. 139, p. 95 - 104$$p95 - 104$$q139<95 - 104$$tSolid state ionics$$v139$$x0167-2738$$y2001
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000029433 9201_ $$0I:(DE-Juel1)VDB35$$d31.12.2003$$gIFF$$kIFF-EKM$$lElektrokeramische Materialien$$x0
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