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@ARTICLE{Krmer:29694,
author = {Krämer, M. and Müller, Ri. and Bovensmann, H. and
Burrows, J. and Brinkmann, J. and Röth, E. P. and Grooß,
J. U. and Müller, Rolf and Woyke, Th. and Ruhnke, R. and
Günther, G. and Hendricks, P. V. and Lippert, E. and
Carslaw, K. S. and Peter, Th. and Zieger, A. and Brühl, Ch.
and Steil, B. and Lehmann, R. and McKenna, D. S.},
title = {{I}ntercomparison of stratospheric chemistry models under
polar vortex conditions},
journal = {Journal of atmospheric chemistry},
volume = {45},
issn = {0167-7764},
address = {Dordrecht [u.a.]},
publisher = {Springer Science + Business Media B.V},
reportid = {PreJuSER-29694},
pages = {51 - 77},
year = {2003},
note = {Record converted from VDB: 12.11.2012},
abstract = {Several stratospheric chemistry modules from box, 2-D or
3-D models, have been intercompared. The intercomparison was
focused on the ozone loss and associated reactive species
under the conditions found in the cold, wintertime Arctic
and Antarctic vortices. Comparisons of both gas phase and
heterogeneous chemistry modules show excellent agreement
between the models under constrained conditions for
photolysis and the microphysics of polar stratospheric
clouds. While the mean integral ozone loss ranges from
$4-80\%$ for different 30-50 days long air parcel
trajectories, the mean scatter of model results around these
values is only about $+/-1.5\%.$ In a case study, where the
models employed their standard photolysis and microphysical
schemes, the variation around the mean percentage ozone loss
increases to about $+/-7\%.$ This increased scatter of model
results is mainly due to the different treatment of the PSC
microphysics and heterogeneous chemistry in the models,
whereby the most unrealistic assumptions about PSC processes
consequently lead to the least representative ozone
chemistry. Furthermore, for this case study the model
results for the ozone mixing ratios at different altitudes
were compared with a measured ozone profile to investigate
the extent to which models reproduce the stratospheric ozone
losses. It was found that mainly in the height range of
strong ozone depletion all models underestimate the ozone
loss by about a factor of two. This finding corroborates
earlier studies and implies a general deficiency in our
understanding of the stratospheric ozone loss chemistry
rather than a specific problem related to a particular model
simulation.},
keywords = {J (WoSType)},
cin = {ICG-I},
ddc = {540},
cid = {I:(DE-Juel1)VDB47},
pnm = {Chemie und Dynamik der Geo-Biosphäre},
pid = {G:(DE-Juel1)FUEK257},
shelfmark = {Environmental Sciences / Meteorology $\&$ Atmospheric
Sciences},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000183325000004},
doi = {10.1023/A:1024056026432},
url = {https://juser.fz-juelich.de/record/29694},
}