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@ARTICLE{Lalah:29975,
author = {Lalah, J. O. and Schramm, K.-W. and Severin, G. F. and
Lenoir, D. and Henkelmann, F. A. and Behechti, A. and
Günther, K. and Kettrup, A.},
title = {{I}n vivo metabolism and organ distribution of a branched
14{C}-nonylphenol isomer in pond snails, {L}ymnaea stagnalis
{L}.},
journal = {Aquatic toxicology},
volume = {62},
issn = {0166-445X},
address = {Amsterdam [u.a.]},
publisher = {Elsevier Science},
reportid = {PreJuSER-29975},
pages = {305 - 319},
year = {2003},
note = {Record converted from VDB: 12.11.2012},
abstract = {The branched isomers of p-nonylphenol (NP) are perceived to
be more resistant to biodegradation in aquatic environments
as well as to have more estrogen-like toxicity than the
straight chain isomers. By use of GC-MS, some of them have
been identified and found to exist in higher concentrations
in the isomeric compound mixture than the straight chain
isomers. The investigations of the distribution and
metabolism of these branched isomers in aquatic organisms
are therefore considered to be important in understanding
the mechanisms of toxicity of NP. A single tertiary isomer
of NP, 4(3'-,6'-dimethyl-3'-heptyl)-phenol, was synthesized
in the laboratory and used in in vivo studies of its organ
distribution and metabolism in Lymnaea stagnalis L.,
following a constant exposure of the organisms to C-14-NP
isomer in water over a period of 8 days at an average
exposure concentration of 105 ppb (range: 93-116 ppb). The
results obtained clearly showed the distribution and
bioconcentration of the isomer residues in various internal
organs of Lymnaea after uptake in water and food. Analysis
of the extracts of the organ tissues and faeces by HPLC and
GC- MS after digestion with Pankreatin/beta-glucuronidase
and nitric acid, respectively, showed that the isomer was
metabolized by conjugation to glucuronic acid and
hydroxylation to a catechol. The findings from these studies
and their implications in the biotransformation and
estrogenicity of NP in Lymnaea stagnalis L. are further
discussed in detail in this paper. (C) 2002 Elsevier Science
B.V. All rights reserved.},
keywords = {J (WoSType)},
cin = {ICG-III},
ddc = {570},
cid = {I:(DE-Juel1)VDB49},
pnm = {Chemie und Dynamik der Geo-Biosphäre},
pid = {G:(DE-Juel1)FUEK257},
shelfmark = {Marine $\&$ Freshwater Biology / Toxicology},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000181265200004},
doi = {10.1016/S0166-445X(02)00106-6},
url = {https://juser.fz-juelich.de/record/29975},
}