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@ARTICLE{Meyer:30193,
author = {Meyer, R. and Waser, R. and Helmbold, A. W. and Borchardt,
G.},
title = {{O}bservation of vacancy defect migration in the cation
sublattice of complex oxides by 18{O} tracer experiments},
journal = {Physical review letters},
volume = {90},
issn = {0031-9007},
address = {College Park, Md.},
publisher = {APS},
reportid = {PreJuSER-30193},
pages = {105901-1 - 105901-4},
year = {2003},
note = {Record converted from VDB: 12.11.2012},
abstract = {We report on O-18 tracer diffusion experiments and model
calculations for the study of cation vacancy migration in
oxide crystals. The model takes advantage of the
electrostatic coupling forces between anion and cation
defects that allow the evolution of the cation vacancy
profile to be observed by anion tracer experiments. Applied
to SrTiO3, the ambipolar diffusion of strontium vacancies
with H-A = 3.5 eV was found to be the dominant
reequilibration mechanism of the cation sublattice. This
result is in contrast to earlier studies proposing the
formation of SrO intergrowth phases.},
keywords = {J (WoSType)},
cin = {IFF-EKM},
ddc = {550},
cid = {I:(DE-Juel1)VDB35},
pnm = {Kondensierte Materie},
pid = {G:(DE-Juel1)FUEK242},
shelfmark = {Physics, Multidisciplinary},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000181597500028},
pubmed = {pmid:12689009},
doi = {10.1103/PhysRevLett.90.105901},
url = {https://juser.fz-juelich.de/record/30193},
}