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000030220 0247_ $$2DOI$$a10.1016/j.jcrysgro.2003.10.026
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000030220 084__ $$2WoS$$aCrystallography
000030220 084__ $$2WoS$$aMaterials Science, Multidisciplinary
000030220 084__ $$2WoS$$aPhysics, Applied
000030220 1001_ $$0P:(DE-HGF)0$$aHe, J. Q.$$b0
000030220 245__ $$aMicrostructure and interfaces of HfO2 thin films grown on silicon substrates
000030220 260__ $$aAmsterdam [u.a.]$$bElsevier$$c2004
000030220 300__ $$a295 - 303
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000030220 440_0 $$03235$$aJournal of Crystal Growth$$v262$$x0022-0248
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000030220 520__ $$aThe microstructure and the interfaces of HfO2 films deposited by metal-organic chemical vapor deposition directly on silicon (0 0 1) substrates were investigated by means of transmission electron microscopy. For two different precursors, Hf(O-i-but)O-2(mmp)(2) and Hf(diethyl-amide)(4), electron diffraction analysis showed a gradual transformation from the amorphous phase to the monoclinic phase in the deposition temperature range of 350-600degreesC. At an intermediate substrate temperature, 550degreesC, a small amount of tetragonal second phase was additionally observed. For the two types of precursors, the thickness of the interfacial amorphous layer was found to depend on the deposition temperature and showed a major decrease along with the amorphous to crystalline transition of the films. The influence of the substrate surface preparation and of post deposition annealing on the thickness of the interfacial layer is also discussed. (C) 2003 Elsevier B.V. All rights reserved.
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000030220 65320 $$2Author$$ainterfacial layers
000030220 65320 $$2Author$$atransmission electron microscopy
000030220 65320 $$2Author$$athin films
000030220 65320 $$2Author$$aHfO2
000030220 65320 $$2Author$$agate oxide
000030220 7001_ $$0P:(DE-HGF)0$$aTeren, A.$$b1
000030220 7001_ $$0P:(DE-Juel1)VDB5020$$aJia, C. L.$$b2$$uFZJ
000030220 7001_ $$0P:(DE-Juel1)VDB22206$$aErhart, P.$$b3$$uFZJ
000030220 7001_ $$0P:(DE-Juel1)VDB4950$$aUrban, K.$$b4$$uFZJ
000030220 7001_ $$0P:(DE-Juel1)131022$$aWaser, R.$$b5$$uFZJ
000030220 7001_ $$0P:(DE-HGF)0$$aWang, R. H.$$b6
000030220 773__ $$0PERI:(DE-600)1466514-1$$a10.1016/j.jcrysgro.2003.10.026$$gVol. 262, p. 295 - 303$$p295 - 303$$q262<295 - 303$$tJournal of crystal growth$$v262$$x0022-0248$$y2004
000030220 8567_ $$uhttp://dx.doi.org/10.1016/j.jcrysgro.2003.10.026
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