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@ARTICLE{Haag:30388,
author = {Haag, W. and Kärcher, B. and Schaefers, S. and Stetzer, O.
and Möhler, O. and Schurath, U. and Krämer, M. and
Schiller, C.},
title = {{N}umerical simulations of homogeneous freezing processes
in the aerosol chamber {AIDA}},
journal = {Atmospheric chemistry and physics},
volume = {3},
issn = {1680-7316},
address = {Katlenburg-Lindau},
publisher = {EGU},
reportid = {PreJuSER-30388},
pages = {195 - 210},
year = {2003},
note = {Record converted from VDB: 12.11.2012},
abstract = {The homogeneous freezing of supercooled H2SO4/H2O aerosols
in an aerosol chamber is investigated with a microphysical
box model using the activity parameterization of the
nucleation rate by Koop et al. (2000). The simulations are
constrained by measurements of pressure, temperature, total
water mixing ratio, and the initial aerosol size
distribution, described in a companion paper (Mohler et al.,
2003). Model results are compared to measurements conducted
in the temperature range between 194 and 235 K, with cooling
rates in the range between 0.5 and 2.6 K min(-1), and at air
pressures between 170 and 1000 hPa. The simulations focus on
the time history of relative humidity with respect to ice,
aerosol size distribution, partitioning of water between gas
and particle phase, onset times of freezing, freezing
threshold relative humidities, aerosol chemical composition
at the onset of freezing, and the number of nucleated ice
crystals. The latter four parameters can be inferred from
the experiments, the former three aid in interpreting the
measurements. Sensitivity studies are carried out to address
the relative importance of uncertainties of basic quantities
such as temperature, total H2O mixing ratio, aerosol size
spectrum, and deposition coefficient of H2O molecules on
ice. The ability of the numerical simulations to provide
detailed explanations of the observations greatly increases
confidence in attempts to model this process under real
atmospheric conditions, for instance with regard to the
formation of cirrus clouds or polar stratospheric ice
clouds, provided that accurate temperature and humidity
measurements are available.},
keywords = {J (WoSType)},
cin = {ICG-I},
ddc = {550},
cid = {I:(DE-Juel1)VDB47},
pnm = {Chemie und Dynamik der Geo-Biosphäre},
pid = {G:(DE-Juel1)FUEK257},
shelfmark = {Meteorology $\&$ Atmospheric Sciences},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000181074900001},
url = {https://juser.fz-juelich.de/record/30388},
}