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| Home > Publications database > In situ STM Study of the Initial Stages of Electrochemical Oxide Formation at the Ag(111)/0.1M NaOH(aq) Interface > print |
| 001 | 31348 | ||
| 005 | 20180210132728.0 | ||
| 024 | 7 | _ | |2 DOI |a 10.1016/j.elecom.2003.10.027 |
| 024 | 7 | _ | |2 WOS |a WOS:000188507400007 |
| 037 | _ | _ | |a PreJuSER-31348 |
| 041 | _ | _ | |a eng |
| 082 | _ | _ | |a 540 |
| 084 | _ | _ | |2 WoS |a Electrochemistry |
| 100 | 1 | _ | |a Staikov, G. |b 0 |u FZJ |0 P:(DE-Juel1)VDB13645 |
| 245 | _ | _ | |a In situ STM Study of the Initial Stages of Electrochemical Oxide Formation at the Ag(111)/0.1M NaOH(aq) Interface |
| 260 | _ | _ | |a Amsterdam [u.a.] |b Elsevier Science |c 2004 |
| 300 | _ | _ | |a 132 - 137 |
| 336 | 7 | _ | |a Journal Article |0 PUB:(DE-HGF)16 |2 PUB:(DE-HGF) |
| 336 | 7 | _ | |a Output Types/Journal article |2 DataCite |
| 336 | 7 | _ | |a Journal Article |0 0 |2 EndNote |
| 336 | 7 | _ | |a ARTICLE |2 BibTeX |
| 336 | 7 | _ | |a JOURNAL_ARTICLE |2 ORCID |
| 336 | 7 | _ | |a article |2 DRIVER |
| 440 | _ | 0 | |a Electrochemistry Communications |x 1388-2481 |0 1775 |v 6 |
| 500 | _ | _ | |a Record converted from VDB: 12.11.2012 |
| 520 | _ | _ | |a The atomic structure of surface layers and the local changes of surface morphology during the initial stages of anodic oxidation of Ag(111) in an aqueous 0.1 M NaOH solution have been investigated by in situ scanning tunneling microscopy (STM) under different polarization conditions. The surface oxide formation starts at underpotentials, i.e. at electrode potentials E below the Nernst-potential E-3DAg2O (vs. SHE) = 0.4 V for the formation of the three-dimensional (3D) bulk Ag2O phase. An ordered overlayer showing distinct Moire pattern is observed in the potential range -0.1 V < E (vs. SHE) < 0.1 V. The appearance of the Moire structure is assigned to the strong OH adsorption, which induces a stretching of the 2D lattice of the OH-terminated topmost Ag(111) monolayer. In situ STM imaging at higher potentials (0.1 V < E (vs. SHE) < 0.3 V) shows the occurrence of a Ag dissolution process followed by an underpotential oxide formation in agreement with previous electrochemical measurements and in situ X-ray absorption studies. (C) 2003 Elsevier B.V. All rights reserved. |
| 536 | _ | _ | |a Kondensierte Materie |c M02 |2 G:(DE-HGF) |0 G:(DE-Juel1)FUEK242 |x 0 |
| 588 | _ | _ | |a Dataset connected to Web of Science |
| 650 | _ | 7 | |a J |2 WoSType |
| 653 | 2 | 0 | |2 Author |a silver |
| 653 | 2 | 0 | |2 Author |a STM |
| 653 | 2 | 0 | |2 Author |a adsorption |
| 653 | 2 | 0 | |2 Author |a electrochemical oxide formation |
| 653 | 2 | 0 | |2 Author |a solid/liquid interface |
| 700 | 1 | _ | |a Kunze, J. |b 1 |0 P:(DE-HGF)0 |
| 700 | 1 | _ | |a Strehblow, H.-H. |b 2 |0 P:(DE-HGF)0 |
| 773 | _ | _ | |a 10.1016/j.elecom.2003.10.027 |g Vol. 6, p. 132 - 137 |p 132 - 137 |q 6<132 - 137 |0 PERI:(DE-600)2027290-X |t Electrochemistry communications |v 6 |y 2004 |x 1388-2481 |
| 856 | 7 | _ | |u http://dx.doi.org/10.1016/j.elecom.2003.10.027 |
| 909 | C | O | |o oai:juser.fz-juelich.de:31348 |p VDB |
| 913 | 1 | _ | |k M02 |v Kondensierte Materie |l Kondensierte Materie |b Materie |0 G:(DE-Juel1)FUEK242 |x 0 |
| 914 | 1 | _ | |a Nachtrag |y 2004 |
| 915 | _ | _ | |0 StatID:(DE-HGF)0010 |a JCR/ISI refereed |
| 920 | 1 | _ | |k ISG-3 |l Institut für Grenzflächen und Vakuumtechnologien |d 31.12.2006 |g ISG |0 I:(DE-Juel1)VDB43 |x 0 |
| 970 | _ | _ | |a VDB:(DE-Juel1)31964 |
| 980 | _ | _ | |a VDB |
| 980 | _ | _ | |a ConvertedRecord |
| 980 | _ | _ | |a journal |
| 980 | _ | _ | |a I:(DE-Juel1)PGI-3-20110106 |
| 980 | _ | _ | |a UNRESTRICTED |
| 981 | _ | _ | |a I:(DE-Juel1)PGI-3-20110106 |
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