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000032121 0247_ $$2DOI$$a10.1103/PhysRevLett.91.016106
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000032121 084__ $$2WoS$$aPhysics, Multidisciplinary
000032121 1001_ $$0P:(DE-Juel1)VDB5414$$aIbach, H.$$b0$$uFZJ
000032121 245__ $$aThe Step Line Tension on a Metal Electrode
000032121 260__ $$aCollege Park, Md.$$bAPS$$c2003
000032121 300__ $$a016106
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000032121 520__ $$aThe step line tension in electrochemical systems differs conceptually from the line tension on metals in the vacuum because it refers to different boundary conditions. A procedure is established for calculating the electrochemical line tension and is applied to a novel model of the interface comprising both a stepped metal electrode and an electrolyte solution. To first order, the potential dependence of the line tension is governed by the energy of the step dipole in the electric field of the space charge in the solution.
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000032121 7001_ $$0P:(DE-HGF)0$$aSchmickler, W.$$b1
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000032121 8567_ $$uhttp://hdl.handle.net/2128/2154$$uhttp://dx.doi.org/10.1103/PhysRevLett.91.016106
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