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005     20200423203547.0
017 _ _ |a This version is available at the following Publisher URL: http://prl.aps.org
024 7 _ |a 10.1103/PhysRevLett.91.016106
|2 DOI
024 7 _ |a WOS:000183915400041
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024 7 _ |a 2128/2154
|2 Handle
037 _ _ |a PreJuSER-32121
041 _ _ |a eng
082 _ _ |a 550
084 _ _ |2 WoS
|a Physics, Multidisciplinary
100 1 _ |a Ibach, H.
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|u FZJ
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245 _ _ |a The Step Line Tension on a Metal Electrode
260 _ _ |a College Park, Md.
|b APS
|c 2003
300 _ _ |a 016106
336 7 _ |a Journal Article
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336 7 _ |a article
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440 _ 0 |a Physical Review Letters
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|v 91
500 _ _ |a Record converted from VDB: 12.11.2012
520 _ _ |a The step line tension in electrochemical systems differs conceptually from the line tension on metals in the vacuum because it refers to different boundary conditions. A procedure is established for calculating the electrochemical line tension and is applied to a novel model of the interface comprising both a stepped metal electrode and an electrolyte solution. To first order, the potential dependence of the line tension is governed by the energy of the step dipole in the electric field of the space charge in the solution.
536 _ _ |a Kondensierte Materie
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588 _ _ |a Dataset connected to Web of Science
650 _ 7 |a J
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700 1 _ |a Schmickler, W.
|b 1
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773 _ _ |a 10.1103/PhysRevLett.91.016106
|g Vol. 91, p. 016106
|p 016106
|q 91<016106
|0 PERI:(DE-600)1472655-5
|t Physical review letters
|v 91
|y 2003
|x 0031-9007
856 7 _ |u http://dx.doi.org/10.1103/PhysRevLett.91.016106
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