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000032155 084__ $$2WoS$$aChemistry, Analytical
000032155 084__ $$2WoS$$aElectrochemistry
000032155 1001_ $$0P:(DE-HGF)0$$aHamad, I. A.$$b0
000032155 245__ $$aElectrosorption of Br and Cl on Ag(1 0 0) - Experiments and Computer Simulations
000032155 260__ $$aNew York, NY [u.a.]$$bElsevier$$c2003
000032155 300__ $$a211 - 219
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000032155 440_0 $$03261$$aJournal of Electroanalytical Chemistry$$v554-555$$x0022-0728
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000032155 520__ $$aWe present chronocoulometry experiments and equilibrium Monte Carlo simulations for the electrosorption of Br and Cl on Ag(1 0 0) single-crystal electrode surfaces. Two different methods are used to calculate the long-range part of the adsorbate-adsorbate interactions. The first method is a truncated-sum approach, while the second is a mean-field-enhanced truncated-sum approach. To compare the two methods, the resulting isotherms are fit to experimental adsorption isotherms, assuming both a constant electrosorption valency gamma and also a coverage-dependent gamma. While a constant gamma fits the Br/Ag(1 0 0) well, a coverage-dependent or potential-dependent gamma is needed for Cl/Ag(1 0 0). (C) 2003 Elsevier B.V. All rights reserved.
000032155 536__ $$0G:(DE-Juel1)FUEK252$$2G:(DE-HGF)$$aMaterialien, Prozesse und Bauelemente für die  Mikro- und Nanoelektronik$$cI01$$x0
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000032155 65320 $$2Author$$abromine electrosorption
000032155 65320 $$2Author$$achlorine electrosorption
000032155 65320 $$2Author$$achronocoulometry
000032155 65320 $$2Author$$acontinuous phase transition
000032155 65320 $$2Author$$alattice-gas model
000032155 65320 $$2Author$$aMonte Carlo simulation
000032155 7001_ $$0P:(DE-Juel1)VDB5443$$aWandlowski, T.$$b1$$uFZJ
000032155 7001_ $$0P:(DE-HGF)0$$aBrown, G.$$b2
000032155 7001_ $$0P:(DE-HGF)0$$aRikvold, P. A.$$b3
000032155 773__ $$0PERI:(DE-600)1491150-4$$a10.1016/S0022-0728(03)00178-5$$gVol. 554-555, p. 211 - 219$$p211 - 219$$q554-555<211 - 219$$tJournal of electroanalytical chemistry$$v554-555$$x0022-0728$$y2003
000032155 8567_ $$uhttp://dx.doi.org/10.1016/S0022-0728(03)00178-5
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000032155 9141_ $$y2003
000032155 915__ $$0StatID:(DE-HGF)0010$$aJCR/ISI refereed
000032155 9201_ $$0I:(DE-Juel1)VDB43$$d31.12.2006$$gISG$$kISG-3$$lInstitut für Grenzflächen und Vakuumtechnologien$$x0
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