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@ARTICLE{Hamad:32155,
author = {Hamad, I. A. and Wandlowski, T. and Brown, G. and Rikvold,
P. A.},
title = {{E}lectrosorption of {B}r and {C}l on {A}g(1 0 0) -
{E}xperiments and {C}omputer {S}imulations},
journal = {Journal of electroanalytical chemistry},
volume = {554-555},
issn = {0022-0728},
address = {New York, NY [u.a.]},
publisher = {Elsevier},
reportid = {PreJuSER-32155},
pages = {211 - 219},
year = {2003},
note = {Record converted from VDB: 12.11.2012},
abstract = {We present chronocoulometry experiments and equilibrium
Monte Carlo simulations for the electrosorption of Br and Cl
on Ag(1 0 0) single-crystal electrode surfaces. Two
different methods are used to calculate the long-range part
of the adsorbate-adsorbate interactions. The first method is
a truncated-sum approach, while the second is a
mean-field-enhanced truncated-sum approach. To compare the
two methods, the resulting isotherms are fit to experimental
adsorption isotherms, assuming both a constant
electrosorption valency gamma and also a coverage-dependent
gamma. While a constant gamma fits the Br/Ag(1 0 0) well, a
coverage-dependent or potential-dependent gamma is needed
for Cl/Ag(1 0 0). (C) 2003 Elsevier B.V. All rights
reserved.},
keywords = {J (WoSType)},
cin = {ISG-3},
ddc = {540},
cid = {I:(DE-Juel1)VDB43},
pnm = {Materialien, Prozesse und Bauelemente für die Mikro- und
Nanoelektronik},
pid = {G:(DE-Juel1)FUEK252},
shelfmark = {Chemistry, Analytical / Electrochemistry},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000185658500022},
doi = {10.1016/S0022-0728(03)00178-5},
url = {https://juser.fz-juelich.de/record/32155},
}