000032204 001__ 32204
000032204 005__ 20190625111330.0
000032204 0247_ $$2DOI$$a10.1016/S0013-4686(02)00740-5
000032204 0247_ $$2WOS$$aWOS:000180995600010
000032204 0247_ $$2altmetric$$aaltmetric:21810494
000032204 037__ $$aPreJuSER-32204
000032204 041__ $$aeng
000032204 082__ $$a540
000032204 084__ $$2WoS$$aElectrochemistry
000032204 1001_ $$0P:(DE-HGF)0$$aMárquez, K.$$b0
000032204 245__ $$aIn Situ FTIR Monitoring of Ag and Au Electrodeposition on Glassy Carbon and Silicon
000032204 260__ $$aNew York, NY [u.a.]$$bElsevier$$c2003
000032204 300__ $$a711 - 720
000032204 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article
000032204 3367_ $$2DataCite$$aOutput Types/Journal article
000032204 3367_ $$00$$2EndNote$$aJournal Article
000032204 3367_ $$2BibTeX$$aARTICLE
000032204 3367_ $$2ORCID$$aJOURNAL_ARTICLE
000032204 3367_ $$2DRIVER$$aarticle
000032204 440_0 $$01776$$aElectrochimica Acta$$v48$$x0013-4686$$y6
000032204 500__ $$aRecord converted from VDB: 12.11.2012
000032204 520__ $$aFormation of Ag, Au and Ag-Au alloys on Si and Glassy Carbon (GC) electrodes from alkaline cyanide electrolytes was investigated using a combination of electrochemical and spectroscopic techniques. Metal deposition and dissolution processes could be studied in situ by monitoring the v(CN) bands of the metal complexes and the, free cyanide ion in the region between 2000 and 2200 cm(-1) using FTIR reflectance spectroscopy. Under the experimental conditions, two different silver complexes, namely [Ag(CN)(2)](-) and [Ag(CN)(3)](2-) (whilst only one gold complex, namely [Au(CN)(2)](-)), were identified. In the case of the Ag-Au alloys, both species co-deposit even in the activation region, where Ag reduction is expected to be the main reaction. Experimental results indicate that in a mixed electrolyte containing equal amounts of Ag and Au, Ag deposition is thermodynamically favoured ( E-eq(0), (Ag)>E-eq(0), (Au)), while Au deposition is kinetically favoured. The Ag-Au alloy deposition follows a progressive nucleation mechanism even at relatively high negative potentials. The morphology and adhesion of all deposits, as well as the alloy composition, were found to be strongly dependent on the deposition conditions. A better adhesion of the films with a higher Au content was observed, due to the formation of a more stable Au-Si bond. (C) 2002 Elsevier Science Ltd. All rights reserved.
000032204 536__ $$0G:(DE-Juel1)FUEK252$$2G:(DE-HGF)$$aMaterialien, Prozesse und Bauelemente für die  Mikro- und Nanoelektronik$$cI01$$x0
000032204 588__ $$aDataset connected to Web of Science
000032204 650_7 $$2WoSType$$aJ
000032204 65320 $$2Author$$aelectrodeposition
000032204 65320 $$2Author$$aFTIR
000032204 65320 $$2Author$$asilver
000032204 65320 $$2Author$$agold
000032204 65320 $$2Author$$asilicon
000032204 65320 $$2Author$$aglassy carbon
000032204 65320 $$2Author$$aalloys
000032204 7001_ $$0P:(DE-HGF)0$$aOritz, R.$$b1
000032204 7001_ $$0P:(DE-HGF)0$$aSchultze, J. W.$$b2
000032204 7001_ $$0P:(DE-HGF)0$$aMárquez, O. P.$$b3
000032204 7001_ $$0P:(DE-Juel1)VDB13645$$aStaikov, G.$$b4$$uFZJ
000032204 773__ $$0PERI:(DE-600)1483548-4$$a10.1016/S0013-4686(02)00740-5$$gVol. 48, p. 711 - 720$$p711 - 720$$q48<711 - 720$$tElectrochimica acta$$v48$$x0013-4686$$y2003
000032204 8567_ $$uhttp://dx.doi.org/10.1016/S0013-4686(02)00740-5
000032204 909CO $$ooai:juser.fz-juelich.de:32204$$pVDB
000032204 9131_ $$0G:(DE-Juel1)FUEK252$$bInformation$$kI01$$lInformationstechnologie mit nanoelektronischen Systemen$$vMaterialien, Prozesse und Bauelemente für die  Mikro- und Nanoelektronik$$x0
000032204 9141_ $$y2003
000032204 915__ $$0StatID:(DE-HGF)0010$$aJCR/ISI refereed
000032204 9201_ $$0I:(DE-Juel1)VDB43$$d31.12.2006$$gISG$$kISG-3$$lInstitut für Grenzflächen und Vakuumtechnologien$$x0
000032204 970__ $$aVDB:(DE-Juel1)34030
000032204 980__ $$aVDB
000032204 980__ $$aConvertedRecord
000032204 980__ $$ajournal
000032204 980__ $$aI:(DE-Juel1)PGI-3-20110106
000032204 980__ $$aUNRESTRICTED
000032204 981__ $$aI:(DE-Juel1)PGI-3-20110106