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@ARTICLE{Wagner:32496,
author = {Wagner, R. and Mangold, A. and Möhler, O. and Saathoff, H.
and Schnaiter, M. and Schurath, U.},
title = {{A} quantitative test of infrared optical constants for
supercooled sulphuric and nitric acid droplet aerosols},
journal = {Atmospheric chemistry and physics},
volume = {3},
issn = {1680-7316},
address = {Katlenburg-Lindau},
publisher = {EGU},
reportid = {PreJuSER-32496},
pages = {1147 - 1164},
year = {2003},
note = {Record converted from VDB: 12.11.2012},
abstract = {In situ Fourier transform infrared (FTIR) extinction
spectra of supercooled H2SO4/ H2O and HNO3/ H2O solution
droplets were recorded in the large coolable aerosol chamber
AIDA (Aerosol Interactions and Dynamics in the Atmosphere)
of Forschungszentrum Karlsruhe for a range of aerosol
compositions and at temperatures extending down to 192 K.
The measured spectra were quantitatively analysed in terms
of aerosol composition and mass concentration by using Mie
theory in combination with published refractive index data
as input parameters. Simultaneously, total sulphuric acid
and nitric acid mass concentrations from filter analysis and
total water concentrations measured with the Lyman-alpha
hygrometer of Forschungszentrum Julich were used to
calculate the aerosol composition at thermodynamic
equilibrium inside the aerosol chamber. By comparing these
measured aerosol parameters with those retrieved from the
analysis of the FTIR spectra, the accuracy of the literature
data sets of refractive indices could be assessed. In
summary, four data sets were tested in the H2SO4/ H2O system
as well as two data sets in the HNO3/ H2O system, partly
revealing significant discrepancies in the retrieved aerosol
properties. Potential explanations for these differences are
discussed in this paper.},
keywords = {J (WoSType)},
cin = {ICG-I},
ddc = {550},
cid = {I:(DE-Juel1)VDB47},
pnm = {Chemie und Dynamik der Geo-Biosphäre},
pid = {G:(DE-Juel1)FUEK257},
shelfmark = {Meteorology $\&$ Atmospheric Sciences},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000184731900001},
url = {https://juser.fz-juelich.de/record/32496},
}