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@ARTICLE{Meier:32649,
author = {Meier, R. and Koglin, E.},
title = {{S}tructure and reactivity of aluminium amidinates in
olefin polymerization},
journal = {Computational materials science},
volume = {27},
issn = {0927-0256},
address = {Amsterdam [u.a.]},
publisher = {Elsevier Science},
reportid = {PreJuSER-32649},
pages = {133 - 137},
year = {2003},
note = {Record converted from VDB: 12.11.2012},
abstract = {Using density functional theory calculations we have
studied ethylene polymerisation activity of experimentally
studied aluminium amidinate homogeneous catalysts. We
confirm an earlier picture for the amidinates that finite
temperature effects need to be considered to rationalize
catalytic activity. Static calculations do not provide any
explanation for the experimentally observed activity. The
tendency to form dinuclear complexes of various kinds makes
this class of species rich in chemistry. The inadequacy of
quantum calculations to provide accurate barriers for
beta-hydrogen transfer for the real experimental systems,
however, renders these systems also as computationally
difficult and a challenge for future studies. (C) 2002
Elsevier Science B.V. All rights reserved.},
keywords = {J (WoSType)},
cin = {ICG-IV},
ddc = {530},
cid = {I:(DE-Juel1)VDB50},
pnm = {Chemie und Dynamik der Geo-Biosphäre},
pid = {G:(DE-Juel1)FUEK257},
shelfmark = {Materials Science, Multidisciplinary},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000181656700023},
doi = {10.1016/S0927-0256(02)00437-8},
url = {https://juser.fz-juelich.de/record/32649},
}